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Aluminum alloy wire |
| RE30465 |
Aluminum alloy wire
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| Patent Drawings: | |
| Inventor: |
Schoerner |
| Date Issued: |
December 30, 1980 |
| Application: |
05/508,223 |
| Filed: |
September 23, 1974 |
| Inventors: |
Schoerner; Roger J. (Carrollton, GA)
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| Assignee: |
Southwire Company (Carrollton, GA) |
| Primary Examiner: |
Dean; R. |
| Assistant Examiner: |
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| Attorney Or Agent: |
Hanegan; Herbert M.Tate; Stanley L.Linne; Robert S. |
| U.S. Class: |
148/437; 428/606 |
| Field Of Search: |
29/183.5; 29/193; 29/193.5; 29/191.6; 75/138; 75/143; 75/148; 75/139; 75/147; 75/142; 75/141; 75/146; 148/32; 148/2; 174/126R |
| International Class: |
C22C 21/00 |
| U.S Patent Documents: |
2252421; 2545866; 3063832; 3241953; 3278300; 3359141; 3397044 |
| Foreign Patent Documents: |
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| Other References: |
Alloy Digest, Aluminum EC, Filing Code: AL-104, Jun. 1961, 2 pp. Published by Engineering Alloys Digest, Inc., Upper Montclair, N. J..
Transactions of the American Society for Metals, the Effect of Single Addition Metals on the Recrystallization, Electrical Conductivity and Rupture Strength of Pure Aluminum, 1949, vol. 41, pp. 443-459..
Japanese Industrial Standard, H2110, 1968..
Russell et al., The Journal of the Institute of Metals, Mar. 1959, pp. 209-219..
Hrivnakova et al., Metal Treatment and Drop Forging, May, 1964, pp. 172-176..
Mould et al., Journal of Materials Science, vol. 2, 1967, pp. 241-255..
Bell Laboratories Record, Aluminum-Conductor Cable an Alternative to Copper, Nov., 1967..
Eversheim, Aluminum, Jul.-Aug., 1955, pp. 338-341..
Domony, Light Metals, Nov., 1949, pp. 614-626..
Lecis et al., International Congress of Aluminum, Jul., 1955, vol. II, pp. 151-155.. |
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| Abstract: |
An aluminum alloy wire having an electrical conductivity of at least sixty-one percent (61%) based on the International Annealed Copper Standard and unexpected properties of increased ultimate elongation, bendability and fatigue resistance when compared to conventional aluminum alloy wire of the same tensile strength. The aluminum alloy wire contains substantially evenly distributed iron aluminate inclusions in a concentration produced by the addition of more than about 0.30 weight percent iron to an alloy mass containing less than about 99.70 weight percent aluminum, no more than 0.15 weight percent silicon, and trace quantities of conventional impurities normally found within a commercial aluminum alloy. The substantially evenly distributed iron aluminate inclusions are obtained by continuously casting an alloy consisting essentially of less than about 99.70 weight percent aluminum, more than 0.30 weight percent iron, no more than 0.15 weight percent silicon and trace quantities of typical impurities to form a continuous aluminum alloy bar, hot-working the bar substantially immediately after casting in substantially that condition in which the bar is cast to form continuous rod which is subsequently drawn into wire without intermediate anneals and annealed after the final draw. After annealing, the wire has the aforementioned novel and unexpected properties of increased ultimate elongation, electrical conductivity of at least sixty-one percent (61%) of the International Annealed Copper Standard, and increased bendability and fatigue resistance. |
| Claim: |
I claim: .[.1. Aluminum alloy rod or wire having a minimum conductivity of sixty-one percent IACS and a diameter or greatest perpendicular distance between parallel faces of between 3.00 inches and0.0031 inches consisting essentially of from about 0.55 to about 0.95 weight percent iron; no more than about 0.15 weight percent silicon; less than 0.05 weight percent each of trace elements selected from the group consisting of vanadium, copper,manganese, magnesium, zinc, boron, and titanium; and from about 98.95 to less than 99.45 weight percent aluminum, said alloy containing no more than 0.15 total weight percent trace elements and having an iron to
silicon ratio of 8:1 orgreater..]. .[.2. Aluminum alloy rod of claim 1 consisting essentially of from about 0.80 to about 0.95 weight percent iron; from about 0.07 to about 0.15 weight percent silicon; and from about 98.95 to about 99.13 weight percent aluminum..]. .[.3. Aluminum alloy wire of claim 1 consisting essentially of from about 0.80 to about 0.95 weight percent iron; from about 0.07 to about 0.15 weight percent silicon; and from about 98.95 to about 99.13 weight percent aluminum..]. .[.4. Aluminum alloywire of claim 1 consisting essentially of from about 0.55 to about 0.80 weight percent iron; from about 0.01 to about 0.07 weight percent silicon; and from about 99.15 to about 99.40 weight percent aluminum..]. .[.5. Aluminum alloy rod of claim 1consisting essentially of from about 0.55 to about 0.80 weight percent iron; from about 0.01 to about 0.07 weight percent silicon; and from about 99.15 to about 99.40 weight percent aluminum..]. .[.6. Aluminum alloy wire of claim 1 consistingessentially of from about 0.55 to less than 0.60 weight percent iron; from about 0.01 to about 0.15 weight percent silicon; and from about 99.10 to about 99.44 weight percent aluminum..]. .[.7. Aluminum alloy rod of claim 1 consisting essentially offrom about 0.55 to less than 0.60 weight percent iron; from about 0.01 to about 0.15 weight percent silicon; and from about 99.10 to
about 99.44 weight percent aluminum..]. 8. Aluminum alloy .[.rod or.]. wire having a minimum conductivity of sixty-one percent IACS and a diameter or greatest perpendicular distance between parallel faces of between .[.3.00.]. .Iadd.0.374.Iaddend.inches and 0.0031 inches and containing substantially evenly distributed iron aluminate inclusions in a concentration produced by the presence of about 0.45 to about 0.95 weight percent iron in an alloy mass consisting essentially of about 98.95to less than 99.45 weight percent aluminum; no more than about 0.15 weight percent silicon; and less than 0.05 weight percent each of trace elements selected from the group consisting of vanadium, copper, maganese, magnesium, zinc, boron, and titanium,said iron aluminate inclusions having a particle size of less than 2,000 angstrom units. .[.9. Aluminum alloy rod of claim 8 wherein iron is present in a concentration of about 0.55 to about 0.95 weight percent; silicon is present in a concentrationof about 0.01 to about 0.15 weight percent; and aluminum is present in a concentration of about 98.95 to about 99.44 weight percent..]. .[.10. Aluminum alloy wire of claim 8 wherein iron is present in a concentration of about 0.55 to about 0.95 weightpercent; silicon is present in a concentration of about 0.01 to about 0.15 weight percent; and aluminum is present in a concentration of about 98.95 to about 99.44 weight percent..]. .[.11. Aluminum alloy rod of claim 8 wherein iron is present in aconcentration of about 0.80 to about 0.95 weight percent; silicon is present in a concentration of about 0.07 to about 0.15 weight percent; and aluminum is present in a concentration of about 98.95 to about 99.13
weight percent..]. 12. Aluminum alloy wire of claim 8 wherein .[.iron is present in a concentration of about 0.80 to about 0.95 weight percent;.]. silicon is present in a concentration of about .Badd..[.0.07.]..Baddend. .Iadd.0.015.Iaddend.to about 0.15 weight percent .[.; and aluminum is present in a concentration of about 98.95 to about 99.13 weight
percent.].. 13. Aluminum alloy wire of claim 8 wherein iron is present in a concentration of about 0.50 to about 0.80 weight percent; silicon is present in a concentration of about .[.0.01.]. .Iadd.0.015 .Iaddend.to about 0.07 weightpercent; aluminum is present in a concentration of about 99.15 to about 99.40 weight percent. .[.14. Aluminum alloy rod of claim 8 wherein iron is present in a concentration of about 0.50 to about 0.80 weight percent; silicon is present in aconcentration of about 0.01 to about 0.07 weight percent; aluminum is present in a concentration of about 99.15 to about 99.40 weight percent..]. .[.15. Aluminum alloy wire of claim 8 wherein iron is present in a concentration of about 0.45 to lessthan 0.60 weight percent; silicon is present in a concentration of about 0.01 to about 0.15 weight percent; and aluminum is present in a concentration of about 99.10 to about 99.54 weight percent..]. .[.16. Aluminum alloy rod of claim 8 wherein ironis present in a concentration of about 0.45 to less than 0.60 weight percent; silicon is present in a concentration of about 0.01 to about 0.15 weight percent; and aluminum is present in a concentration of about 99.10 to about 99.54 weight percent..]. .[.17. Aluminum alloy wire of claim 8 wherein iron is present in a concentration of about 0.55 to less than 0.60 weight percent; silicon is present in a concentration of about 0.01 to about 0.15 weight percent; and aluminum is present in aconcentration of about 99.10 to about 99.44 weight percent..]. .[.18. Aluminum alloy rod of claim 8 wherein iron is present in a concentration of about 0.55 to less than 0.60 weight percent; silicon is present in a concentration of about 0.01 to about0.15 weight percent; and aluminum is present in a concentration of about 99.10 to about 99.44 weight percent..]. .[.19. Aluminum alloy rod or wire of claim 1 wherein the silicon content is from 0.01 to 0.15 weight percent, the individual trace elementcontent is from 0.0001 to 0.05, weight percent and the total trace element content is from 0.004 to 0.15 weight percent..]. .[.20. Aluminum alloy rod or wire of claim 8 wherein the silicon content is from 0.01 to 0.15 weight percent, the individualtrace element content is from 0.0001 to 0.05, and the total trace element content is from 0.004 to 0.15 weight percent..]. .Iadd. 21. Aluminum alloy wire having a minimum conductivity of sixty-one percent IACS and a diameter or greatest perpendiculardistance between parallel faces of between 0.374 inches and 0.0031 inches and containing substantially evenly distributed iron aluminate inclusions in a concentration produced by the presence of about 0.45 to about 0.95 weight percent iron in an alloymass consisting essentially of about 98.95 to less than 99.45 weight percent aluminum; 0.015 to 0.15 weight percent silicon; trace quantities of less than 0.05 weight percent each of trace elements selected from the group consisting of vanadium,copper, manganese, magnesium, zinc, boron, and titanium, and a total trace element content of no more than 0.15 weight percent, said iron aluminate inclusions having a particle size of less than 2,000 angstrom units. .Iaddend. |
| Description: |
This invention relates to an aluminum alloy wire suitable for use as an electrical conductor and more particularly concerns an aluminum alloy wire having an acceptable electrical conductivity and improvedelongation, bendability and tensile strength.
The use of various aluminum alloy wires (conventionally referred to as EC wire) as conductors of electricity is well established in the art. Such alloys characteristically have conductivities of at least sixty-one percent of the InternationalAnnealed Copper Standard (hereinafter sometimes referred to as IACS) and chemical constituents consisting of a substantial amount of pure aluminum and small amounts of conventional impurities such as silicon, vanadium, iron, copper, manganese, magnesium,zinc, boron and titanium. The physical properties of prior aluminum alloy wire have proven less than desirable in many applications. Generally desirable percent elongations have been obtained only at less than desirable tensile strengths and desirabletensile strengths have been obtainable only at less than desirable percent elongations. In addition, the bendability and fatigue resistance of prior aluminum alloy wires has been so low that the prior wire has been generally unsuitable for manyotherwise desirable applications.
Thus, it becomes apparent that a need has arisen within the industry for an aluminum alloy electrically conductive wire which has both improved percent elongation and improved tensile strength, and also possesses an ability to withstand numerousbends at one point and to resist fatiguing during use of the conductor. Therefore, it is an object of the present invention to provide an aluminum alloy wire of acceptable conductivity and improved physical properties such that the conductor may be usedin new applications. Another object of the present invention is to provide an aluminum alloy wire having novel properties of increased ultimate elongation and tensile strength, improved bendability and fatigue resistance and acceptable electricalconductivity. These and other objects, features and advantages of the present invention will become apparent to those skilled in the art from a consideration of the following detailed description of the invention.
In accordance with this invention, the present aluminum alloy electrically conductive wire is prepared from an alloy comprising less than about 99.70 weight percent aluminum, more than about 0.30 weight percent iron, and no more than 0.15 weightpercent silicon. Preferably, the aluminum content of the present alloy comprises from about 98.95 to less than about 99.45 weight percent with particularly superior results being achieved when from about 99.15 to about 99.40 weight percent aluminum isemployed. Preferably, the iron content of the present alloy comprises about 0.45 weight percent to about 0.95 weight percent with particularly superior results being achieved when from about 0.50 weight percent to about 0.80 weight percent iron isemployed. Preferably, no more than 0.07 weight percent silicon is employed in the present alloy. The ratio between the percentage iron and the percentage silicon must be 1.99:1 or greater. Preferably, the ratio between percentage iron and percentagesilicon is 8:1 or greater. Thus, if the present aluminum alloy contains an amount of iron within the low area of the present range for iron content, the percentage of aluminum must be increased rather than increasing the percentage of silicon outsidethe ratio limitation previously specified. It has been found that properly processed wire having aluminum alloy constituents which fall within the above-specified ranges possesses acceptable electrical conductivity and improved tensile strength andultimate elongation and in addition has a novel unexpected property of surprisingly increased bendability and fatigue resistance.
The present aluminum alloy is prepared by initially melting and alloying aluminum with the necessary amounts of iron or other constituents to provide the requisite alloy for processing. Normally, the content of silicon is maintained as low aspossible without adding additional amounts to the melt. Typical impurities or trace elements are also present within the melt, but only in trace quantities such as less than 0.05 weight percent each with a total content of trace impurities generally notexceeding 0.15 weight percent. Of course, when adjusting the amounts of trace elements due consideration must be given to the conductivity of the final alloy since some trace elements affect conductivity more severely than others. The typical traceelements include vanadium, copper, manganese magnesium, zinc, boron and titanium. If the content of titanium is relatively high (but still quite low compared to the aluminum, iron and silicon content), small amounts of boron may be added to tie-up theexcess titanium and keep it from reducing the conductivity of the wire.
Iron is the major constituent added to the melt to produce the alloy of the present invention. Normally, about 0.50 weight percent is added to the typical aluminum component used to prepare the present alloy. Of course, the scope of the presentinvention includes the addition of more or less iron together with the adjustment of the content of all alloying constituents.
After alloying, the melted aluminum composition is continuously cast into a continuous bar. The bar is then hot-worked in substantially that condition in which it is received from the casting machine. A typical hot-working operation comprisesrolling the bar in a rolling mill substantially immediately after being cast into a bar.
One example of a continuous casting and rolling operation capable of producing continuous rod as specified in this application is as follows:
A continuous casting machine serves as a means for solidifying the molten aluminum alloy metal to provide a cast bar that is conveyed in substantially the condition in which it solidified from the continuous casting machine to the rolling mill,which serves as a means for hot-forming the cast bar into rod or another hot-formed product in a manner which imparts substantial movement to the cast bar along a plurality of angularly disposed axes.
The continuous casting machine is of conventional casting wheel type having a casting wheel with a casting groove partially closed by an endless belt supported by the casting wheel and an idler pulley. The casting wheel and the endless beltcooperate to provide a mold into one end of which molten metal is poured to solidify and from the other end of which the cast bar is emitted in substantially that condition in which it is solidified.
The rolling mill is of conventional type having a plurality of roll stands arranged to hot-form the cast bar by a series of deformations. The continuous casting machine and the rolling mill are positioned relative to each other so that the castbar enters the rolling mill substantially immediately after solidification and in substantially that condition in which it solidified. In this condition, the cast bar is at a hot-forming temperature within the range of temperatures for hot-forming thecast bar at the initiation of hot-forming without heating between the casting machine and the rolling mill. In the event that it is desired to closely control the hot-forming temperature of the cast bar within the conventional range of hot-formingtemperatures, means for adjusting the temperature of the cast bar may be placed between the continuous casting machine and the rolling mill without departing from the inventive concept disclosed herein.
The roll stands each include a plurality of rolls which engage the cast bar. The rolls of each roll stand may be two or more in number and arranged diametrically opposite from one another or arranged at equally spaced positions about the axis ofmovement of the cast bar through the rolling mill. The rolls of each roll stand of the rolling mill are rotated at a predetermined speed by a power means such as one or more electric motors and the casting wheel is rotated at a speed generallydetermined by its operating characteristics. The rolling mill serves to hot-form the cast bar into a rod of a cross-sectional area substantially less than that of the cast bar as it enters the rolling mill.
The peripheral surfaces of the rolls of adjacent roll stands in the rolling mill change in configuration; that is, the cast bar is engaged by the rolls of successive roll stands with surfaces of varying configuration, and from differentdirections. This varying surface engagement of the cast bar in the roll stands functions to knead or shape the metal in the cast bar in such a manner that it is worked at each roll stand and also to simultaneously reduce and change the cross-sectionalarea of the cast bar into that of the rod.
As each roll stand engages the cast bar, it is desirable that the cast bar be received with sufficient volume per unit for time at the roll stand for the cast bar to generally fill the space defined by the rolls of the roll stand so that therolls will be effective to work the metal in the cast bar. However, it is also desirable that the space defined by the rolls of each roll stand not be overfilled so that the cast bar will not be forced into the gaps between the rolls. Thus, it isdesirable that the rod be fed toward each roll stand at a volume per unit of time which is sufficient to fill, but not overfill, the space defined by the rolls of the roll stand.
As the cast bar is received from the continuous casting machine, it usually has one large flat surface corresponding to the surface of the endless band and inwardly tapered side surfaces corresponding to the shape of the groove in the castingwheel. As the cast bar is compressed by the rolls of the roll stands, the cast bar is deformed so that it generally takes the cross-sectional shape defined by the adjacent peripheries of the rolls of each roll stand.
Thus, it will be understood that with this apparatus, cast aluminum alloy rod of an infinite number of different lengths is prepared by simultaneous casting of the molten aluminum alloy and hot-forming or rolling the cast aluminum bar.
The continuous rod produced by the casting and rolling operation is then processed in a reduction operation designed to produce continuous wire of various gauges. The unannealed rod (i.e., as rolled to .function. temper) is cold-drawn through aseries of progressively constricted dies, without intermediate anneals, to form a continuous wire of desired diameter. At the conclusion of this drawing operation, the alloy wire will have an excessively high tensile strength and an unacceptably lowultimate elongation, plus a conductivity below that which is industry accepted as the minimum for an electrical conductor, i.e., sixty-one percent of IACS. The wire is then annealed or partially annealed to obtain a desired tensile strength and cooled. At the conclusion of the annealing operation, it is found that the annealed wire has the properties of acceptable conductivity and improved tensile strength together with unexpectedly improved percent ultimate elongation and surprisingly increasedbendability and fatigue resistance as specified previously in this application. The annealing operation may be continuous as in resistance annealing, induction annealing, convection annealing by continuous furnaces or radiation annealing by continuousfurnaces, or, preferably, may be batch annealed in a batch furnace. When continuously annealing, temperatures of about 450.degree. F. to about 1200.degree. F. may be employed with annealing times of about five minutes to about 1/10,000 of a minute. Generally, however, continuous annealing temperatures and times may be adjusted to meet the requirements of the particular overall processing operation so long as the desired tensile strength is achieved. In a batch annealing operation, a temperature ofapproximately 400.degree. F. to about 750.degree. F. is employed with residence times of about thirty (30) minutes to about twenty-four (24) hours. As mentioned with respect to continuous annealing, in batch annealing the times and temperatures may bevaried to suit the overall process so long as the desired tensile strength is obtained. Simply by way of example, it has been found that the following tensile strengths in the present aluminum wire are achieved with the listed batch annealingtemperature and times.
TABLE I ______________________________________ Temperature Tensile strength (.degree. F.) Time (hrs.) ______________________________________ 12,000-14,000 650 3 14,000-15,000 550 3 15,000-17,000 520 3 17,000-22,000 480 3 ______________________________________
During the continuous casting of this alloy, a substantial portion of the iron present in the alloy precipitates out of solution as iron aluminate intermetallic compound (FeAl.sub.3). Thus, after casting, the bar contains a dispersion ofFeAl.sub.3 in a supersaturated solid solution matrix. The supersaturated matrix may contain as much as 0.17 weight percent iron. As the bar is rolled in a hot-working operation immediately after casing, the FeAl.sub.3 particles are broken up anddispersed throughout the matrix inhibiting large cell formation. When the rod is then drawn to its final gauge size without intermediate anneals and then aged in a final annealing operation, the tensile strength, elongation and bendability are increaseddue to the small cell size and the additional pinning of dislocations by preferential precipitation of FeAl.sub.3 on the dislocation sites. Therefore, new dislocation sources must be activated under the applied stress of the drawing operation and thiscauses both the strength and the elongation to be further improved.
The properties of the present aluminum alloy wire are significantly affected by the size of the FeAl.sub.3 particles in the matrix. Coarse precipitates reduce the percent elongation and bendability of the wire by enhancing nucleation and thus,formation of large cells which, in turn, lowers the recrystallization temperature of the wire. Fine precipitates improve the percent elongation and bendability by reducing nucleation and increasing the recrystallization temperature. Grossly coarseprecipitates of FeAl.sub.3 cause the wire to become brittle and generally unusable. Coarse precipitates have a particle size of above 2,000 angstrom units and fine precipitates have a particle size of below 2,000 angstrom units.
A typical alloy No. 12 AWG wire of the present invention has physical properties of 15,000 p.s.i. tensile strength, ultimate elongation of 20%, conductivity of 61% IACS, and bendability of 20 bends to break. Ranges of physical propertiesgenerally provided by No. 12 AWG wire prepared from the present alloy include tensile strengths of about 12,000 to about 22,000 p.s.i. ultimate elongations of about 40% to about 5%, conductivities of about 61% to about 63% and number of bends to breakof about 45 to 10.
A more complete understanding of the invention will be obtained from the following examples.
EXAMPLE 1
A comparison between prior EC aluminum alloy wire and the present aluminum alloy wire is provided by preparing a prior EC alloy with aluminum content of 99.73 weight percent, iron content of 0.18 weight percent, silicon content of 0.059 weightpercent, and trace amounts of typical impurities. The present alloy is prepared with aluminum content of 99.45 weight percent, iron content of 0.45 weight percent, silicon content of 0.056 weight percent, and trace amounts of typical impurities. Bothalloys are continuously cast into continuous bars and hot-rolled into continuous rod in similar fashion. The alloys are then cold-drawn through successively constricted dies to yield #12 AWG continuous wire. Sections of the wire are collected onseperate bobbins and batch furnace-annealed at various temperatures and for various lengths of time to yield sections of the prior EC alloy and the present alloy of varying tensile strengths. Several samples of each section are tested in a devicedesigned to measure the number of bends required to break each sample at a particular flexure point. Through uniform force and tension, the device fatigues each sample through an arc of approximately 135.degree.. The wire is bent across a pair ofspaced opposed mandrels having a diameter equal to that of the wire. The mandrels are spaced apart a distance of about one and one-half times the diameter of the wire. One bend is recorded after the wire is deflected from a vertical disposition to oneextreme of the arc, returned back to vertical, deflected to the opposite extreme of the arc, and returned back to the original vertical disposition. The speed of deflection, force and tension are substantially equal for all tested samples. The resultsare as follows:
TABLE II-A ______________________________________ EC alloy Present alloy Tensile No. of bends Tensile Average No. of strength to break strength bends to break ______________________________________ 10,083 431/2 13,500 44 12,788 24 14,30043 13,480 211/2 15,100 36 14,168 14 16,025 291/2 15,200 133/4 17,050 23 16,100 11 17,134 18 17,125 93/4 18,253 14 18,186 83/4 19,571 13 23,069 51/2 25,286 43/4 29,309 4 35,986 31/2 ______________________________________
As shown in Table II-A, the present alloy has a surprisingly improved property of bendability over conventional EC alloy.
Several samples of the present alloy #12 AWG wire and EC alloy #12 AWG wire, processed as previously specified, are then tested for percent ultimate elongation by standard testing procedures. At the instant of breakage, the increase in length ofthe wire is measured. The percent ultimate elongation is then figured by dividing the initial length of the wire sample into the increase in length of the wire sample. The tensile strength of the wire sample is recorded as the pounds per square inch ofcross-sectional diameter required to break the wire during the percent ultimate elongation test. The results are as follows:
TABLE II-B ______________________________________ EC alloy Present alloy Tensile Percent ulti- Tensile Percent ulti- strength mate elongation strength mate elongation ______________________________________ 10,000 30.5 13,500 30.8 12,70021 14,300 30 13,500 14 15,525 24 14,200 11.5 16,150 19 15,000 8 16,550 16 16,500 3.5 17,200 13.2 18,300 2 18,270 8.6 19,000 6.7 ______________________________________
As shown in Table II-B, the present alloy has a surprisingly improved property of percent ultimate elongation over conventional EC alloy.
EXAMPLES 2 THROUGH 7
Six aluminum alloys are prepared with varying amounts of major constituents. Those alloys are reported in the following table:
TABLE III ______________________________________ Example No. Percent Al Percent Fe Percent Si ______________________________________ 2 99.73 0.180 0.059 3 99.52 0.385 0.063 4 99.46 0.450 0.056 5 99.36 0.540 0.064 6 99.275 0.680 0.015 799.20 0.750 0.030 ______________________________________
The six alloys are then cast into six continuous bars and hot-rolled into six continuous rods. The rods are cold-drawn through successively constricted dies to yield #12 gauge wire. The wire produced from the alloys of Examples 2 and 4 areresistance annealed and the remainder of the examples are batch furnace annealed to yield the tensile strengths reported in Table IV. After annealing, each of the wires is tested for percent conductivity, tensile strength, percent ultimate elongationand average number of bends to break by standard testing procedures for each, except that the procedure specified in Example 1 is used for determining average number of bends to break. These results are reported in the following table.
TABLE IV ______________________________________ Conductiv- ity in Percent Average percent Tensile ultimate No. of bends Example No. IACS strength elongation to break ______________________________________ 2 62.8 15,150 8.1 151/2 3 61.315.153 28.0 271/2 5 61.5 15.152 37.5 28 61.5 15,152 35.0 281/2 6 61.25 14,300 28.0 32 7 61.2 15,800 25 28 ______________________________________
From a review of these results, it may be seen that Example 2 falls outside the scope of the present invention in percentage of components. In addition, it will be noted for Example 2 that the percentage of ultimate elongation is somewhat lowerthan desirable and the average number of bends to break the sample is lower than the remaining examples.
EXAMPLE 8
An aluminum alloy is prepared with an aluminum content of 99.42 weight percent, iron content of 0.50 weight percent, silicon content of 0.055 weight percent and trace amounts of typical impurities. The alloy is cast into a continuous bar whichis hot-rolled to yield a continuous rod. The rod is then cold-drawn through successively constricted dies to yield #12 AWG wire. The wire is collected on a 30 inch bobbin until the collected wire weighs approximately 250 pounds. The bobbin is thenplaced in a cold General Electric Bell Furnace and the temperature therein is raised to 480.degree. F. The temperature of the furnace is held at 480.degree. F. for three hours after which the heat is terminated and the furnace cools to 400.degree. F.The furnace is then quick cooled and the bobbin is removed. Under testing, it is found that the alloy wire has a conductivity of 16.6% IACS, a tensile strength of 16,500 p.s.i., a percentage of ultimate elongation of 20%, and a number of bends to breakof 18.
EXAMPLE 9
Example 8 is repeated except the Bell Furnace temperature is raised to 500.degree. F. and held for three hours prior to cooling. The annealed alloy wire has a conductivity of 61.4% IACS, a tensile strength of 15,000 p.s.i., a percentage ofultimate elongation of 27%, and a number of bends to break of 28.
EXAMPLE 10
Example 8 is repeated except the Bell Furnace temperature is raised to 600.degree. F. and held for three hours prior to cooling. The annealed alloy wire has a conductivity of 61.2% IACS, a tensile strength of 14,000 p.s.i., a percentage ofelongation of 30%, and a number of bends to break of 43.
EXAMPLE 11
Example 8 is repeated except the Bell Furnace temperature is raised to 600.degree. F. and held 11/2 hours prior to cooling. The annealed alloy has a conductivity of 61.5% IACS, a tensile strength of 16,000 p.s.i., a percentage of elongation of22%, and a number of bends to break of 23.
EXAMPLE 12
The alloy of Example 8 is cast into a continuous bar which is hot-rolled to yield a continuous .function. temper rod of 3/8 inch diameter. The rod is then cold-drawn through successively constricted dies to yield #14 AWG wire. The wire is thenredrawn on a Synchro Model BG-16 wire drawing machine which includes a Synchro Resistoneal continuous in line annealer. The wire is drawn to #28 AWG at a finishing speed of 3,300 feet per minute and the in line annealer is operated at 52 volts withtransformer tap setting at No. 8. The annealed alloy wire has a conductivity of 62% IAS, a tensile strength of 15,450 p.s.i., and a percentage of ultimate elongation of 25%. Since the wire gauge is so small, the number of bends to break is extremelylarge.
EXAMPLE 13
The alloy of Example 8 is cast into a continuous bar which is hot-rolled to yield a continuous .function. temper rod of 3/8 inch diameter. The rod is then cold-drawn on a Synchro Style No. FX13 wire drawing machine which includes a continuousin line annealer. The rod is drawn to #12 AWG wire at a finishing speed of 2,000 feet per minute and the in line annealer voltage at preheater #1 is 35 volts, at preheater #2 is 35 volts, and at the annealer is 22 volts. The three transformer taps areset at #5. The annealed alloy wire has a conductivity of 62% IACS, a tensile strength of 16,300 p.s.i., and a percentage of ultimate elongation of 20%.
For the purpose of clarity, the following terminology used in this application is explained as follows:
Rod--A solid product that is long in relation to its cross-section. Rod normally has a cross-section between three inches and 0.375 inches.
Wire--A solid wrought product that is long in relation to its cross-section, which is square or rectangunlar with sharp or rounded corners or edges, or is round, a regular hexagon or a regular octagon, and whose diameter or greatest perpendiculardistance between parallel faces is between 0.374 inches and 0.0031 inches.
While this invention has been described in detail with particular reference to preferred embodiments thereof, it will be understood that variations and modifications can be effected within the spirit and scope of the invention as describedhereinbefore and as defined in the appended claims.
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