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Robert J. Saxton Patents
Inventor:
Saxton; Robert J.
Address:
West Chester, PA
No. of patents:
34
Patents:




Patent Number Title Of Patent Date Issued
7205446 Conversion of unsaturated chemicals to oligomers April 17, 2007
An oligomerization process in which hydrocarbon feedstocks are contacted with a hydrotreating catalyst in the absence of hydrogen and in the liquid phase. The catalyst is a heterogeneous catalyst selected from supported reduced metals, metals oxides, metal sulfides and combinations t
7094389 Chabazite-containing molecular sieve, its synthesis and its use in the conversion of oxygenates August 22, 2006
A crystalline material substantially free of framework phosphorus and comprising a CHA framework type molecular sieve with stacking faults or at least one intergrown phase of a CHA framework type molecular sieve and an AEI framework type molecular sieve, wherein said material, in its
7067108 Chabazite-type molecular sieve, its synthesis and its use in the conversion of oxygenates to ole June 27, 2006
The synthesis of a crystalline material, in particular a high silica zeolite, having a chabazite-type framework is aided by the addition to the synthesis mixture of seeds of an AEI framework-type material. The chabazite-type product has a relatively small crystal size and exhibits ac
7008610 AEI-Type zeolite, its synthesis and its use in the conversion of oxygenates to olefins March 7, 2006
A crystalline material is described that has an AEI framework type, wherein the material, in its calcined, anhydrous form, has a composition involving the molar relationship: (n)X.sub.2O.sub.3:YO.sub.2, wherein X is a trivalent element, Y is a tetravalent element n is from 0 to less
6884916 Conversion of unsaturated chemicals to oligomers April 26, 2005
An oligomerization process in which hydrocarbon feedstocks are contacted with a hydrotreating catalyst in the absence of hydrogen and in the liquid phase. The catalyst is a heterogeneous catalyst selected from supported reduced metals, metals oxides, metal sulfides and combinations there
6702945 Ionic membranes for organic sulfur separation from liquid hydrocarbon solutions March 9, 2004
Methods for the separation of sulfur compounds from a hydrocarbon mixture using an ionic membrane are provided. Preferred ionic membranes are Nafion.RTM.-type (polymers of perfluorosulfonic acid) membranes and derivatives thereof. Preferred applications include the removal of sulfur
6649061 Membrane process for separating sulfur compounds from FCC light naphtha November 18, 2003
A process for the separation of sulfur compounds from a hydrocarbon mixture using a membrane is provided. Preferred hydrocarbon mixtures are oil refining fractions such as light cracked naphtha. Membranes are composed of either ionic or non-ionic materials and preferentially permeate sul
5792721 Preparation of phosphomolybdovanadate polyoxoanions August 11, 1998
The present invention provides a process for the preparation of acidic aqueous solutions consisting essentially of, phosphomolybdovanadate salts. Certain processes of the present invention dissolve in water an oxide, oxoacid, or mixtures thereof, and at least one oxoanion salt of pho
5695736 Tiatanium containing molecular sieve having a zelite beta structure December 9, 1997
A crystalline molecular sieve having a framework structure isomorphous with zeolite beta and containing Si and Ti, but essentially no framework Al, usefully catalyzes olefin epoxidation wherein hydrogen peroxide is the oxidant.
5688484 Non-hydrothermal method of making a titanium-containing zeolite November 18, 1997
A process for producing a titanium-containing zeolite such as TS-1 titanium silicalite is disclosed. A precursor mixture comprising a silica source such as tetraalkylorthosilicate, a titanium source such as titanium alkoxide, a growth medium comprising a nitrogen-containing organic base
5684170 Epoxidation process November 4, 1997
A crystalline molecular sieve having a framework structure isomorphous with zeolite beta and containing Si and Ti, but essentially no framework Al, usefully catalyzes olefin epoxidation wherein hydrogen peroxide is the oxidant.
5681789 Activation of as-synthesized titanium-containing zeolites October 28, 1997
An as-synthesized zeolite having titanium substituted in its lattice framework and containing an organic template such as a quaternary ammonium salt may be activated for use as a catalyst by treating said as-synthesized zeolite with ozone. At least partial removal and/or reaction of
5679749 Olefin epoxidation using niobium-containing zeolites October 21, 1997
Molecular sieve zeolites containing niobium isomorphously substituted in their framework lattice are obtained by hydrothermal crystallization using quaternary ammonium templates. The zeolites are useful catalysts, particularly for the oxidation of hydrocarbons such as olefins.
5663384 Asymetric epoxidation using a titanium-containing zeolite and a chiral hydroperoxide September 2, 1997
Prochiral ethylenically unsaturated substrates are converted to chiral epoxides by reaction with optically active hydroperoxides in the presence of titanium-containing zeolites such as titanium zeolite beta. The method is particularly suitable for producing epoxides from unsubstituted
5621122 Epoxidation process April 15, 1997
A crystalline molecular sieve having a framework structure isomorphous with zeolite beta and containing Si and Ti, but essentially no framework Al, usefully catalyzes olefin epoxidation wherein hydrogen peroxide or an organic hydroperoxide is utilized as the oxidizing agent.
5618512 Niobium-containing zeolites April 8, 1997
Molecular sieve zeolites containing niobium isomorphously substituted in their framework lattice are obtained by hydrothermal crystallization using quaternary ammonium templates. The zeolites are useful catalysts, particularly for the oxidation of hydrocarbons such as olefins.
5557014 Catalytic system for olefin oxidation to carbonyl products September 17, 1996
The present invention provides aqueous catalyst solutions useful for oxidation of olefins to carbonyl products, comprising a palladium catalyst and a polyoxoacid or polyoxoanion oxidant comprising vanadium. It also provides processes for oxidation of olefins to carbonyl products, com
5554356 Method of making essentially silicic zeolite beta September 10, 1996
A molecular sieve having a zeolite beta morphology, but essentially free of alumina, is prepared from a silicon oxide source in high yield by a hydrothermal crystallization in the presence of a diquaternary templating agent. The templating agent may be derived from a diamine such as
5527520 Method of making a titanium-containing molecular sieve June 18, 1996
A crystalline molecular sieve having a framework structure isomorphous with zeolite beta and containing Si and Ti, but essentially no framework Al, usefully catalyzes olefin epoxidation wherein hydrogen peroxide or an organic hydroperoxide is utilized as the oxidizing agent.
5508019 Dealumination of aluminosilicates April 16, 1996
Crystalline aluminosilicates such as zeolite beta may be readily dealuminated using organic sulfonic acids such as methanesulfonic acid to provide useful catalysts or catalyst precursors. A high degree of aluminum removal with minimal loss of crystallinity is possible even when an or
5506363 Catalytic system for olefin oxidation to carbonyl products April 9, 1996
The present invention provides aqueous catalyst solutions useful for oxidation of olefins to carbonyl products, comprising a palladium catalyst, a polyoxoacid or polyoxoanion oxidant comprising vanadium, and chloride ions. It also provides processes for oxidation of olefins to carbon
5474754 Preparation of an aluminosilicotitanate isomorphous with zeolite beta December 12, 1995
Aluminosilicotitanates having a framework structure isomorphous with zeolite beta are prepared by heating a solid amorphous SiO.sub.2 --TiO.sub.2 --Al.sub.2 O.sub.3 cogel which has been impregnated with a quaternary tetraethyl ammonium species. The aluminosilicotitanates, which are u
5453511 Bis-piperidinium compounds September 26, 1995
A crystalline molecular sieve having a framework structure isomorphous with zeolite beta and containing Si and Ti, but essentially no framework Al, usefully catalyzes olefin epoxidation wherein hydrogen peroxide or an organic hydroperoxide is utilized as the oxidizing agent.
5412122 Epoxidation process May 2, 1995
Olefins are epoxidized by hydrogen peroxide in the presence of a modified titanium-containing molecular sieve having a framework structure isomorphous with zeolite beta and comprised of Si, Ti, and Al. The molecular sieve is modified by substituting the aluminum-associated cationic s
5374747 Epoxidation process and catalyst therefore December 20, 1994
A crystalline molecular sieve having a framework structure isomorphous with zeolite beta and containing Si and Ti, but essentially no framework Al, usefully catalyzes olefin epoxidation wherein hydrogen peroxide is the oxidant.
5241118 Process for the preparation of trisubstituted ureas by reductive carbonylation August 31, 1993
A process for preparing trisubstituted ureas is disclosed. A nitroarene is reacted with carbon monoxide and a secondary amine in the presence of a Group VIII transition metal catalyst and optionally one or more promoters selected from primary amines, halide ion-containing compounds, and
5233095 Process for manufacture of resorcinol August 3, 1993
A process for the manufacture of resorcinol is described which relies upon the intermediacy of a .alpha.,.beta.-unsaturated ketone which can be reacted with a hydroxy moiety-containing compound to obtain a resorcinol precursor which is subsequently converted to resorcinol. In a specific
5116796 Organic solvent soluble oxide supported hydrogenation catalyst precursors May 26, 1992
The present invention discloses two polyoxoanion supported metal complexes found to be useful in olefin hydrogenation. The complexes are novel compositions of matter which are soluble in organic solvents. In particular, the compositions of matter comprise A.sub.x [L.sub.n Ir.sup.(I)
5026942 Process for selective diisopropylation of naphthyl compounds using shape selective acidic crysta June 25, 1991
The selective isopropylation of a naphthyl compound to diisopropylnaphthalene enhanced in the 2,6-diisopropylnaphthalene isomer is obtained in the presence of an acidic crystalline molecular sieve catalyst having twelve membered oxygen rings. The catalyst pore aperture dimension rang
5003122 Process for selective diisopropylation of naphthyl compounds using shape selective acidic crysta March 26, 1991
The selective isopropylation of a naphthyl compound to diisopropylnaphthalene enhanced in the 2,6-diisopropylnaphthalene isomer is obtained in the presence of an acidic crystalline molecular sieve catalyst having twelve membered oxygen rings. The catalyst pore aperture dimension rang
4861921 Process for manufacture of resorcinol August 29, 1989
A process for the manufacture of resorcinol is described which relies upon the intermediacy of a .alpha.,.beta.-unsaturated ketone which can be reacted with a hydroxy moiety-containing compound to obtain a resorcinol precursor which is subsequently converted to resorcinol. In a specific
4853357 Olefin oxidation catalyst system August 1, 1989
The additional of redox-active metal components and ligands, alternatively or simultaneously, results in increased conversion and selectivity in the palladium-catalyzed oxidation of olefins to carbonyl products in the presence of polyoxoanions. In preferred modes, heteropolyoxoanions and
4723041 Olefin oxidation catalyst system February 2, 1988
The addition of redox-active metal components and ligands, alternatively or simultaneously, results in increased conversion and selectivity in the palladium-catalyzed oxidation of olefins to carbonyl products in the presence of polyoxoanions. In preferred modes, heteropolyoxoanions and
4720474 Olefin oxidation catalyst system January 19, 1988
The addition of redox-active metal components and ligands, alternatively or simultaneously, results in increased conversion and selectivity in the palladium-catalyzed oxidation of olefins to carbonyl products in the presence of polyoxoanions. In preferred modes, heteropolyoxoanions and


 
 
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