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Max P. McDaniel Patents
Inventor:
McDaniel; Max P.
Address:
Bartlesville, OK
No. of patents:
249
Patents:


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Patent Number Title Of Patent Date Issued
RE31443 Treatment of silica November 15, 1983
A silica-containing composition suitable for supporting chromium to produce a catalyst capable of giving high melt flow olefin polymers for such applications as injection molding and the like requiring a narrow molecular weight distribution, is produced by treating a silica-containing
RE31390 Treatment of silica September 20, 1983
A silica-containing composition suitable for supporting chromium to produce a catalyst capable of giving high melt flow olefin polymers for such applications as injection molding and the like requiring a narrow molecular weight distribution, is produced by treating a silica-containing
7417097 Organometal compound catalyst August 26, 2008
This invention provides catalyst compositions that are useful for polymerizing at least one monomer to produce a polymer. This invention also provides catalyst compositions that are useful for polymerizing at least one monomer to produce a polymer, wherein said catalyst composition c
7390764 Organometal catalyst compositions June 24, 2008
This invention provides catalyst compositions that are useful for polymerizing at least one monomer to produce a polymer This invention also provides catalyst compositions that are useful for polymerizing at least one monomer to produce a polymer, wherein said catalyst composition co
7312283 Polymerization catalysts and process for producing bimodal polymers in a single reactor December 25, 2007
Catalyst compositions comprising a first metallocene compound, a second metallocene compound, an activator-support, and an organoaluminum compound are provided. Methods for preparing and using such catalysts to produce polyolefins are also provided. The compositions and methods discl
7307133 Polymers having broad molecular weight distributions and methods of making the same December 11, 2007
Methods of polymerizing at least one olefin include contacting the olefin with a catalyst comprising chromium and with a cocatalyst comprising a non-transition metal cyclopentadienyl (Cp) compound. The polymerization may be performed in the presence of hydrogen. Using the cocatalyst in
7294599 Acidic activator-supports and catalysts for olefin polymerization November 13, 2007
This invention relates to the field of olefin polymerization catalyst compositions, and methods for the polymerization and copolymerization of olefins, typically using a supported catalyst composition. In one aspect, this invention encompasses precontacting a metallocene with an olefin o
7271124 Process to produce polymers September 18, 2007
A process to produce ethylene polymers is provided.
7247594 Catalysts for olefin polymerization July 24, 2007
This invention relates to the field of olefin polymerization catalyst compositions, and methods for the polymerization and copolymerization of olefins, including polymerization methods using a catalyst composition. One aspect of this invention is the formation and use of a catalyst c
7230128 Organometallic fluorenyl compounds, preparations, and use June 12, 2007
Fluorenyl-containing metallocenes are disclosed along with methods for making the metallocenes. Also disclosed are methods for using the metallocenes as polymerization catalysts. In addition, polymers resulting from such polymerizations are disclosed.
7214642 Methods of preparing active chromium/alumina catalysts via treatment with sulfate May 8, 2007
Methods of preparing a polymerization catalyst are provided that include contacting a support comprising alumina with a sulfating agent and with chromium. In an embodiment in which the chromium is provided from a chromium compound such as chromium oxide, the support may be calcined a
7208441 Polymerization catalyst systems and processes therefor and therewith April 24, 2007
A copolymer of ethylene and a higher alpha olefin, preferably 1-hexene, can be produced using an activated chromium containing catalyst system and a cocatalyst selected from the group consisting of trialkylboron, trialkylsiloxyalutninum, and a combination of trialkylboron and thalkyl
7199073 Resins that yield low haze films and the process for their production April 3, 2007
Catalyst compositions comprising a first metallocene compound, a second metallocene compound, a third metallocene compound, a chemically-treated solid oxide, and an organoaluminum compound are provided. Methods for preparing and using the catalyst and polyolefins are also provided. The
7163906 Organochromium/metallocene combination catalysts for producing bimodal resins January 16, 2007
This invention relates to the field of olefin polymerization catalyst compositions, and methods for the polymerization and copolymerization of olefins, including polymerization methods using a supported catalyst composition. In one aspect, the present invention encompasses a catalyst
7148298 Polymerization catalysts for producing polymers with low levels of long chain branching December 12, 2006
This invention relates to catalyst compositions, methods, and polymers encompassing a Group 4 metallocene with bridging .eta..sup.5-cyclopentadienyl-type ligands, in combination with a cocatalyst and an activator-support. The compositions and methods disclosed herein provide ethylene
7119153 Dual metallocene catalyst for producing film resins with good machine direction (MD) elmendorf t October 10, 2006
This invention relates to catalyst compositions comprising a first metallocene compound, a second metallocene compound, at least one chemically-treated solid oxide, and at least one organoaluminum compound. This invention also relates to methods to prepare and use the catalyst compos
7119043 Olefin polymerization processes and products thereof October 10, 2006
A novel loop/slurry olefin polymerization process is provided which produces ultra high molecular weight ethylene homopolymers and ultra high molecular weight ethylene copolymers. Catalyst systems used are selected from the group consisting of inorganic oxide supported titanium-conta
7112643 Polymers having low levels of long chain branching and methods of making the same September 26, 2006
Methods of producing a polymer include contacting at least one olefin with a catalyst prepared by contacting a support comprising alumina with a sulfating agent and with chromium. Polymer compositions produced in this manner may exhibit relatively low levels of long chain branching and
7109277 Polymerization catalysts September 19, 2006
A process to produce a polymer is provided. The process comprising contacting a treated solid oxide compound, an organometal compound, and an organoaluminum compound in the presence of an alpha olefin under polymerization conditions to produce the polymer.
7094857 Ethylene polymers and copolymers with high optical opacity August 22, 2006
This invention relates to the field of metal-catalyzed olefin polymerization methods and the polymers and films prepared therefrom. In one aspect, this invention provides polyethylene and ethylene/.alpha.-olefin copolymers formed in the presence of tightly-bridged metallocene catalys
7071276 Process to produce polymers July 4, 2006
A process to produce ethylene polymers is provided.
7041753 Organometal catalyst compositions May 9, 2006
This invention provides oxide matrix compositions that can be utilized in catalyst compositions that are useful for polymerizing at least one monomer to produce a polymer. The oxide matrix composition comprises residual mineral components and an oxide precursor. The catalyst composit
7041617 Catalyst compositions and polyolefins for extrusion coating applications May 9, 2006
This invention relates to the field of olefin polymerization catalyst compositions, and methods for the polymerization and copolymerization of olefins, including polymerization methods using a supported catalyst composition. In one aspect, the present invention encompasses a catalyst
7026494 Polymerization catalysts for producing high melt index polymers without the use of hydrogen April 11, 2006
Various catalyst compositions including the contact product of at least one ansa-metallocene compound, at least one organoaluminum compound, and at least one activator-support are disclosed. Processes for forming such compositions and for forming polyolefins with such compositions are al
7022781 Polymerization catalyst systems and processes using alkyl lithium compounds as a cocatalyst April 4, 2006
A catalyst system composition comprising a chromium compound supported on a silica-titania support, wherein said catalyst system has been reduced with carbon monoxide, and a cocatalyst selected from the group consisting of i) alkyl lithium compounds, ii) dialkyl aluminum alkoxides in
7001968 Olefin polymerization processes and products thereof February 21, 2006
A novel loop/slurry olefin polymerization process is provided which produces ultra-high molecular weight ethylene homopolymer.
6992032 Organometal catalyst compositions January 31, 2006
This invention provides catalyst compositions that are useful for polymerizing at least one monomer to produce a polymer. This invention also provides catalyst compositions that are useful for polymerizing at least one monomer to produce a polymer, wherein said catalyst composition c
6984603 Organometal catalyst compositions January 10, 2006
This invention provides catalyst compositions that are useful for polymerizing at least one monomer to produce a polymer. This invention also provides catalyst compositions that are useful for polymerizing at least one monomer to produce a polymer, wherein said catalyst composition c
6982306 Stannoxy-substituted metallocene catalysts for olefin and acetylene polymerization January 3, 2006
This invention relates to the field of olefin polymerization catalyst compositions, and methods for the polymerization and copolymerization of olefins, including polymerization methods using a catalyst composition. One aspect of this invention is the formation and use of a catalyst c
6977235 Catalyst systems comprising a calcined chromium catalyst and a non-transition metal cyclopentadi December 20, 2005
According to an embodiment, catalyst systems for polymerizing olefins include a catalyst comprising chromium and a cocatalyst comprising a substituted or unsubstituted non-transition metal cyclopentadienyl compound (Cp). The catalyst also comprises an inorganic oxide support. In an e
6936667 Polymerization catalyst compositions and processes to produce polymers and bimodal polymers August 30, 2005
A process to produce a first catalyst composition is provided. The process comprises contacting at least one first organometal compound and at least one activator to produce the first catalyst composition. The activator is selected from the group consisting of aluminoxanes, fluoro-organo
6900277 Effect of aluminophosphate on catalyst systems comprising metal alkyl cocatalysts May 31, 2005
Novel catalyst systems which comprise one or more diimine nickel(II) or palladium (II) complexes, one or more cocatalysts, and aluminophosphate are disclosed. Olefin polymerization processes using those catalyst systems are also disclosed. The inclusion of aluminophosphate can improve
6887819 Compositions that can produce polymers May 3, 2005
This invention provides compositions that are useful for polymerizing at least one monomer into at least one polymer.
6878785 Organometal compound catalyst April 12, 2005
This invention provides catalyst compositions that are useful for polymerizing at least one monomer to produce a polymer. This invention also provides catalyst compositions that are useful for polymerizing at least one monomer to produce a polymer, wherein said catalyst composition c
6875835 Polymerization catalyst systems and processes therefor and therewith April 5, 2005
A copolymer of ethylene and a higher alpha olefin, preferably 1-hexene, can be produced using an activated chromium containing catalyst system and a cocatalyst selected from the group consisting of trialkylboron, trialkylsiloxyalutninum, and a combination of trialkylboron and thalkyl
6867278 Olefin polymers, method of making, and use thereof March 15, 2005
The present invention is directed to homo-polymers and copolymers of mono-1-olefins, a method of making such polymers,and uses of such polymers. Polymers of the present invention are formed by contacting at least one mono-1-olefin having from 2 to about 20 carbon atoms per molecule a
6858687 Organometal catalyst compositions February 22, 2005
This invention provides catalyst compositions that are useful for polymerizing at least one monomer to produce a polymer. This invention also provides catalyst compositions that are useful for polymerizing at least one monomer to produce a polymer, wherein said catalyst composition c
6855781 Process to produce polymers February 15, 2005
A process to produce ethylene polymers is provided. Particularly, a process to produce ethylene polymers having a broad molecular weight distribution is provided. More particularly, a process to produce ethylene polymers that have low formation of smoke and odor during blow molding is pr
6838533 Organometal catalyst composition January 4, 2005
This invention provides catalyst compositions that are useful for polymerizing at least one monomer to produce a polymer. This invention also provides catalyst compositions that are useful for polymerizing at least one monomer to produce a polymer, wherein said catalyst composition c
6833338 Organometal compound catalyst December 21, 2004
This invention provides catalyst compositions that are useful for polymerizing at least one monomer to produce a polymer. This invention also provides catalyst compositions that are useful for polymerizing at least one monomer to produce a polymer, wherein said catalyst composition c
6831141 Process for producing polymers December 14, 2004
A process of using a catalyst composition to polymerize at least one monomer to produce a polymer. The process comprises contacting the catalyst composition and at least one monomer in a polymerization zone under polymerization conditions to produce the polymer. The catalyst composit
6828268 Polymerization catalyst systems and processes using alkyl lithium compounds as a cocatalyst December 7, 2004
A catalyst system composition comprising a chromium compound supported on a silica-titania support, wherein said catalyst system has been reduced with carbon monoxide, and a cocatalyst selected from the group consisting of i) alkyl lithium compounds, ii) dialkyl aluminum alkoxides in com
6750302 Organometal catalyst compositions June 15, 2004
A polymerization catalyst is disclosed, wherein the catalyst comprises: (a) a metallocene of Ti, Zr or Hf, (b) an organoaluminum compound, and (c) a treated solid oxide support which comprises fluorine and chromium.
6716938 Polymerization catalyst systems, methods of making and uses therefor April 6, 2004
A novel magnesium treated silica-containing compound that is useful as a support for chromium based olefin polymerization catalyst systems is provided which produces ethylene polymers having with MWD's that promote good properties particularly in HMW film applications.
6713572 Ethylene copolymerization process March 30, 2004
A process as disclosed for producing a low density polyethylene using a particle form polymerization process and a titanium-containing catalyst wherein the ratio of comonomer to ethylene is at least about 1:1 and the titanium-containing catalyst is a special catalyst which has been p
6667274 Polymerization catalysts December 23, 2003
A process to produce a polymer is provided. The process comprising contacting a treated solid oxide compound, an organometal compound, and an organoaluminum compound in the presence of an alpha olefin under polymerization conditions to produce the polymer.
6657034 Olefin polymerization processes and products thereof December 2, 2003
A novel loop/slurry olefin polymerization process is provided which produces ultra high molecular weight ethylene homopolymers and ultra high molecular weight ethylene copolymers. Catalyst systems used are selected from the group consisting of inorganic oxide supported titanium-containin
6657023 Polymerization process December 2, 2003
Polymerization processes for ethylene and at least one mono-1-olefin comonomer having from about three to eight carbon atoms per molecule in the presence of a twice-aged catalyst system comprising chromium supported on a silica-titania support and a trialkylboron compound is provided.
6653416 Polymerization process utilizing organometal catalyst compositions and the polymer produced ther November 25, 2003
This invention provides catalyst compositions that are useful for polymerizing at least one monomer to produce a polymer. This invention also provides catalyst compositions that are useful for polymerizing at least one monomer to produce a polymer, wherein said catalyst composition c
6642324 Process that produces polymers November 4, 2003
A process comprising polymerizing ethylene, or polymerizing ethylene and at least one other olefin, to produce a polymer is provided.
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