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Francois Mathey Patents
Inventor:
Mathey; Francois
Address:
Paris, FR
No. of patents:
14
Patents:




Patent Number Title Of Patent Date Issued
6927262 Bridged biphospholes and metallocenes prepared therefrom August 9, 2005
The invention relates to novel bridged biphosphole ligands according to the general formula: ##STR1##where R.sup.2, R.sup.3, R.sup.4 are chosen from hydrogen, alkyl, aryl or silyl, R.sup.1 is chosen from hydrogen, alkyl, aryl or halogen, R.sup.1 possibly being replaced with a direct
6683208 Optically active diphosphines, preparation thereof according to a process for the resolution of January 27, 2004
New optically active bis[1-phospha-2,3-diphenyl-4,5-dimethylnorbornadiene] diphosphines and new optically active transition metal complexes with said phosphines are described. The complexes are useful as catalysts to promote hydrogenation of substrates.
6632969 Method for separating a diphosphine diastereoisomers October 14, 2003
A process for separating the (d/l) and (meso) diastereoisomers of bis-[1-phospha-2,3-diphenyl-4,5-dimethylnorbornadiene] comprising converting the mixture of diastereoisomers of bis-[1-phospha-2,3-diphenyl-4,5-dimethylnorbornadiene] to a mixture of the corresponding diastereoisomers
6521795 6,6'-bis-(1-phosphanorbornadiene) diphosphines, their preparation and their uses February 18, 2003
A subject of the present invention is new 6,6'-bis-(1-phosphanorbornadiene) diphosphines, their preparation process and their use in asymmetrical catalysis.The new diphosphines correspond to general formula (I): ##STR1##in which R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 are as defined
6417375 Furylphosphines and organometallic complexes containing them July 9, 2002
The present invention relates to novel water-soluble furylphosphines.It also relates to organometallic complexes comprising these furylphosphines and to the use of such complexes.It also relates to the process for the preparation of the water-soluble furylphosphines.
6380412 Optically active diphosphines, preparation thereof according to a process for the resolution of April 30, 2002
The present invention relates to optically active diphosphines. It is also targeted at their preparation according to a process for the resolution of the racemic mixture of the said phosphines to optically active isomers. The subject of the invention is new optically active bis[1-pho
6288279 6',6-bis-(1-phosphanorbornadiene) diphosphines September 11, 2001
A subject of the present invention is new 6,6'-bis-(1-phosphanorbornadiene) diphosphines, their preparation process and their use in asymmetrical catalysis.The new diphosphines correspond to general formula (I): ##STR1##
6166257 Asymmetric hydrogenation method of a ketonic compound and derivative December 26, 2000
The present invention relates to a process for the asymmetric hydrogenation of a ketonic compound and derivative.The invention relates to the use of optically active metal complexes as catalysts for the asymmetric hydrogenation of a ketonic compound and derivative.The process for the asy
6037493 Optically active diphosphines, preparation thereof according to a process for the resolution of March 14, 2000
The present invention relates to optically active diphosphines. It is also targeted at their preparation according to a process for the resolution of the racemic mixture of the said phosphines to optically active isomers.The subject of the invention is new optically active bis[1-phospha-
5783738 Optically active diphosphines, preparation thereof according to a process for the resolution of July 21, 1998
The present invention relates to optically active diphosphines. It is also targeted at their preparation according to a process for the resolution of the racemic mixture of the said phosphines to optically active isomers. The subject of the invention is new optically active bis[1-pho
4504683 Phospholes with functional substituents on the phosphorus and process for the preparation of pho March 12, 1985
The phospholes and P-functional phospholes correspond to the general formula: ##STR1## in which: R.sub.1 and R.sub.2 are identical or different and represent hydrogen or a lower alkyl group of C.sub.1 to C.sub.4 such as a methyl group, and R.sub.3 represents an aryl group (such a
4404147 Process for the synthesis of 1,1-diphosphaferrocenes September 13, 1983
The invention relates to the manufacture of 1,1'-diphosphaferrocenes.The process consists of reacting a mixture of an alkali metal phenyl and an alkali metal phospholyl in the presence of a Lewis acid, in a basic ether, preferably at between -20.degree. and +20.degree. C., and then reacting
4193978 Production of hydrogen March 18, 1980
Method of utilizing lithium borohydride for the storage and generation of hydrogen where the lithium borohydride is thermally decomposed to generate hydrogen and the remaining decomposition products (contaning boron in free or combined form and lithium in free or combined form) are hydro
4173706 Process for producing fluorinated organic compounds containing a difluoromethylene group from co November 6, 1979
A novel process for producing fluorinated organic compounds containing a difluoromethylene group, essentially characterized by reacting organic compounds containing a carbonyl function with molybdenum hexafluoride at room temperature and under atmospheric pressure.


 
 
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