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Luc R. M. Martens Patents
Inventor:
Martens; Luc R. M.
Address:
Meise, BE
No. of patents:
37
Patents:




Patent Number Title Of Patent Date Issued
7384887 Attrition resistant molecular sieve catalysts June 10, 2008
This invention is directed to a hardened molecular sieve catalyst composition, a method of making the composition and a method of using the composition. The catalyst composition is made by mixing together molecular sieve, liquid, and an effective hardening amount of a dried molecular
7381853 Production of higher olefins June 3, 2008
A method of making a higher olefin product from a C.sub.4.sup.+ fraction separated from the hydrocarbon product produced by an oxygenate to olefin reaction unit. The C.sub.4.sup.+ fraction primarily contains butenes which may be directed to a higher olefin reaction unit without removing
7345213 Protecting catalytic activity of a SAPO molecular sieve March 18, 2008
This invention is directed to a method of making an olefin product from an oxygenate feedstock and a method of protecting catalytic activity of a silicoaluminophosphate molecular sieve. The methods comprise providing a silicoaluminophosphate molecular sieve having catalytic sites within
7301065 Molecular-sieve catalyst composition, its making and use in conversion processes November 27, 2007
The invention relates to a molecular sieve catalyst composition, to a method of making or forming the molecular sieve catalyst composition, and to a conversion process using the catalyst composition. In particular, the invention is directed to making a formulated molecular sieve catalyst
7288689 Methanol and fuel alcohol production for an oxygenate to olefin reaction system October 30, 2007
The present invention provides various processes for producing C1 to C4 alcohols, optionally in a mixed alcohol stream, and optionally converting the alcohols to light olefins. In one embodiment, the invention includes directing a first portion of a syngas stream to a methanol synthesis
7271123 Molecular sieve catalyst composition, its making and use in conversion process September 18, 2007
The invention relates to a molecular sieve catalyst composition, to a method of making or forming the molecular sieve catalyst composition, and to a conversion process using the catalyst composition. In particular, the invention is directed to a molecular sieve catalyst composition of a
7253331 Molecular sieve catalyst composition, its making and use in conversion processes August 7, 2007
The invention relates to a molecular sieve catalyst composition, to a method of making or forming the molecular sieve catalyst composition, and to a conversion process using the catalyst composition. In particular, the invention is directed to a conversion process for producing olefi
7238844 Olefin oligomerization July 3, 2007
This invention is to a method of oligomerizing an olefin feed stream. The olefin feed stream contains at least one C.sub.2 to C.sub.12 olefin to obtain an olefin feed stream and has less than 1,000 ppm by weight oxygenated hydrocarbon. The olefin is oligomerized by contacting with an
7230151 Two catalyst process for making olefin June 12, 2007
This invention is to a process of making olefin, particularly ethylene and propylene, from an oxygenate feed. The invention uses two or more zeolite catalysts. Examples of zeolite catalysts include a first catalyst containing of ZSM-5, and a second catalyst containing a 10-ring molecular
7223896 Fines co-feed for maintaining efficient reactor hydrodynamics May 29, 2007
This invention provides processes for maintaining a desired particle size distribution in an oxygenate to olefin reaction system. In one embodiment, the invention comprises replacing lost catalyst fines with less active co-catalyst particles. By adding less active co-catalyst particl
7223714 Method of transferring catalyst in a reaction system May 29, 2007
The invention is directed to methods of transfering catalyst particles into and within reaction systems. The reaction systems are those that use catalysts that comprise molecular sieves, particularly metalloaluminophosphate molecular sieves, especially metalloaluminophosphate molecul
7214844 Molecular sieve catalyst compositions, its making and use in conversion processes May 8, 2007
The invention relates to a molecular sieve catalyst composition, to a method of making or forming the molecular sieve catalyst composition, and to a conversion process using the catalyst composition. In particular, the invention is directed to a making a molecular sieve catalyst comp
7199276 Controlling the ratio of ethylene to propylene produced in an oxygenate to olefin conversion pro April 3, 2007
The present invention provides various processes for producing methanol and ethanol, preferably in a mixed alcohol stream. In one embodiment, the invention includes directing syngas to a synthesis zone wherein the syngas contacts a methanol synthesis catalyst and an ethanol synthesis
7193122 Stabilization of acid catalysts March 20, 2007
The invention is directed to a method of stabilizing metalloaluminophosphate molecular sieves and catalysts derived therefrom. In particular, the invention is directed to a method of treating such molecular sieves with chemisorbed ammonia, which may be easily desorbed before or durin
7160831 Molecular sieve catalyst composition, its making and use in conversion processes January 9, 2007
The invention relates to a molecular sieve catalyst composition, to a method of making or forming the molecular sieve catalyst composition, and to a conversion process using the catalyst composition. In particular, the invention is directed to making a formulated molecular sieve catalyst
7071136 Attrition resistant molecular sieve catalysts July 4, 2006
This invention is directed to a hardened molecular sieve catalyst composition, a method of making the composition and a method of using the composition. The catalyst composition is made by mixing together molecular sieve, liquid, and an effective hardening amount of a dried molecular
6979756 Heat treating a molecular sieve and catalyst December 27, 2005
Disclosed is a method of heat treating a molecular sieve. The method comprises providing a template-containing molecular sieve, heating the molecular sieve under conditions effective to remove a portion of the template from the molecular sieve, and cooling the heated molecular sieve
6897180 Stabilization of acid catalysts May 24, 2005
The invention is directed to a method of stabilizing metalloaluminophosphate molecular sieves and catalysts derived therefrom. In particular, the invention is directed to a method of treating such molecular sieves with chemisorbed ammonia, which may be easily desorbed before or durin
6884914 Olefin oligomerization April 26, 2005
This invention is to a method of oligomerizing an olefin feed stream. The olefin feed stream contains at least one C.sub.2 to C.sub.12 olefin to obtain an olefin feed stream and has less than 1,000 ppm by weight oxygenated hydrocarbon. The olefin is oligomerized by contacting with an
6875899 Production of higher olefins April 5, 2005
A method of making a higher olefin product from a C.sub.4.sup.+ fraction separated from the hydrocarbon product produced by an oxygenate to olefin reaction unit. The C.sub.4.sup.+ fraction primarily contains butenes which may be directed to a higher olefin reaction unit without removing
6872680 Molecular sieve catalyst composition, its making and use in conversion processes March 29, 2005
The invention relates to a molecular sieve catalyst composition, to a method of making or forming the molecular sieve catalyst composition, and to a conversion process using the catalyst composition. In particular, the invention is directed to a making a molecular sieve catalyst composit
6797852 Protecting catalytic activity of a SAPO molecular sieve September 28, 2004
This invention is directed to a method of making an olefin product from an oxygenate feedstock and a method of protecting catalytic activity of a silicoaluminophosphate molecular sieve. The methods comprise providing a silicoaluminophosphate molecular sieve having catalytic sites within
6797851 Two catalyst process for making olefin September 28, 2004
This invention is to a process of making olefin, particularly ethylene and propylene, from an oxygenate feed. The invention uses two or more zeolite catalysts. Examples of zeolite catalysts include a first catalyst containing of ZSM-5, and a second catalyst containing a 10-ring molecular
6787501 Molecular sieve catalyst composition, its making and use in conversion processes September 7, 2004
The invention relates to a molecular sieve catalyst composition, to a method of making or forming the molecular sieve catalyst composition, and to a conversion process using the catalyst composition. In particular, the invention is directed to making a formulated molecular sieve catalyst
6613950 Stripping hydrocarbon in an oxygenate conversion process September 2, 2003
A process for method for the production of olefin product from an oxygenate-containing feedstock includes exposing a silicoaluminophosphate catalyst to an oxygenate-containing feedstock in a reaction zone under conditions effective to convert the oxygenate-containing feedstock to an
6605749 Synthesis of molecular sieve catalysts August 12, 2003
Disclosed is a molecular sieve catalyst which contains molecular sieve-containing attrition particles and virgin molecular sieve, the attrition particles having been recycled from a catalyst manufacture process or from a reaction system. The catalyst can be used in a variety of catal
6541415 Synthesis of molecular sieve catalysts April 1, 2003
Disclosed is a molecular sieve catalyst which contains molecular sieve-containing attrition particles and virgin molecular sieve, the attrition particles having been recycled from a catalyst manufacture process or from a reaction system. The catalyst can be used in a variety of catal
6521562 Preparation of molecular sieve catalysts micro-filtration February 18, 2003
A method of making a molecular sieve catalyst by preparing a catalyst slurry containing molecular sieve, binder and a matrix material and directing the slurry to a forming unit. The catalyst slurry is prepared by using a microfiltration process whereby the molecular sieve is washed and
6509290 Catalyst composition including attrition particles and method for making same January 21, 2003
Disclosed is a molecular sieve catalyst which contains molecular sieve-containing attrition particles and virgin molecular sieve, the attrition particles having been recycled from a catalyst manufacture process or from a reaction system. The catalyst can be used in a variety of catal
6503863 Heat treating a molecular sieve and catalyst January 7, 2003
Disclosed is a method of heat treating a molecular sieve. The method comprises providing a template-containing molecular sieve, heating the molecular sieve under conditions effective to remove a portion of the template from the molecular sieve, and cooling the heated molecular sieve
6482999 Method for improving light olefin selectivity in an oxygenate conversion reaction November 19, 2002
A method for converting oxygenates to light olefins. The method comprises contacting, in a reactor, a feedstock comprising oxygenates with a molecular sieve catalyst under conditions effective to convert the feedstock to a product including light olefins and by-products, the contacti
6455748 Protecting catalytic activity of a SAPO molecular sieve September 24, 2002
This invention is directed to a method of making an olefin product from an oxygenate feedstock and a method of protecting catalytic activity of a silicoaluminophosphate molecular sieve. The methods comprise providing a silicoaluminophosphate molecular sieve having catalytic sites within
6429348 Method for selectively producing propylene by catalytically cracking an olefinic hydrocarbon fee August 6, 2002
The invention provides a method for converting an olefinic hydrocarbon feedstock to propylene comprising: contacting a hydrocarbon feedstock under catalytic cracking conditions with a catalyst comprising a catalyst selected from the group consisting of SAPO catalysts, MeAPO catalysts,
6395674 Heat treating a molecular sieve and catalyst May 28, 2002
Disclosed is a method of heat treating a molecular sieve. The method comprises providing a template-containing molecular sieve, heating the molecular sieve under conditions effective to remove a portion of the template from the molecular sieve, and cooling the heated molecular sieve
6316683 Protecting catalytic activity of a SAPO molecular sieve November 13, 2001
This invention is directed to a method of making an olefin product from an oxygenate feedstock and a method of protecting catalytic activity of a silicoaluminophosphate molecular sieve. The methods comprise providing a silicoaluminophosphate molecular sieve having catalytic sites within
6080303 Zeolite catalyst activity enhancement by aluminum phosphate and phosphorus June 27, 2000
The present invention provides a process for improving the catalytic activity of small and medium pore acidic zeolite catalyst which comprises the steps of treating a zeolite with a phosphorus compound to form a phosphorus treated zeolite and combining the phosphorus treated zeolite
5406002 Zeolite catalyst and catalysed reactions April 11, 1995
An organophosphine-treated titanium-containing zeolite is a catalyst for hydrocarbon oxidation.


 
 
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