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Klaus Bronstert Patents
Inventor:
Bronstert; Klaus
Address:
Carlsberg, DE
No. of patents:
59
Patents:


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Patent Number Title Of Patent Date Issued
5753777 Telechelics containing ethanolamine or oligoether-ol-amine end groups and process for the prepar May 19, 1998
A polydiene which is obtainable by anionic polymerization of a diene using a bifunctional Li initiator followed by polymer-like reaction and which contains at least one ethanolamine or oligoetherolamine terminal group of the general structure I ##STR1## in which R.sup.1 denotes a
5625008 Preparation of telechelic structures April 29, 1997
Telecheles are prepared by reacting, preferably, polyfunctional, living polymers obtained by anionic polymerization with a functionalizing agent by a process in which the reaction is carried out while stirring with a stirrer having knife-like blades as stirring elements, the latter being
5614595 Polymers based on conjugated dienes March 25, 1997
Polymers Ia and Ib carrying functional groups and obtainable byA) 1. hydrogenation of the olefinic double bonds of a polymer IIa comprisinga) from 20 to 100% by weight of a conjugated diene,b) from 0 to 80% by weight of an aromatic vinyl compound, andc) from 0 to 20% by weight of further comonom
5494976 Polymers based on conjugated dienes February 27, 1996
Polymers Ia and Ib carrying functional groups and obtainable byA)1. hydrogenation of the olefinic double bonds of a polymer IIa comprisinga) from 20 to 100% by weight of a conjugated diene,b) from 0 to 80% by weight of an aromatic vinyl compound, andc) from 0 to 20% by weight of further comonomers,t
5332791 Polyisobutylene hydrocarbon or polymer containing a double bond allylic to an end amino group July 26, 1994
Hydrocarbons and polymers thereof, of the structure (I)where R is a hydrocarbon radical, are prepared by reacting corresponding starting materials which contain chlorine bonded to tertiary carbon, of the structurewith from 1 to 10 moles of butadiene in the presence of a Friedel-Crafts ca
5321093 Living polymers, the preparation thereof and the use thereof for preparing telechelic polymers June 14, 1994
A process for preparing bifunctional living polymers which are able to forth bifunctional telechelic polymers or block copolymers with at least 3 blocks of conjugated dienes and/or vinylaromatics with molecular weights of from 1,500 to 500,000, by bifunctional initiators whose anionic ce
5290874 Alkadiene/vinylaromatic copolymers containing side groups, and their use March 1, 1994
The novel alkadiene/vinyl-aromatic copolymers which contain side groups and have a random, block-like or star-like structure and whose polymerized alkadiene comonomer units are partially or completely selectively hydrogenated, and which contain one or more side groups having one or more
5266647 Branched copolymers November 30, 1993
A copolymer with stellate branching, of the general formula [A-].sub.k X, where A is the monovalent radical of a homopolymer, block copolymer or random copolymer of a conjugated diene and/or vinyl-aromatic hydrocarbon, k is a number from 1 to 10, and X is the k-valent radical of a coupli
5212248 Preparation of hydrocarbons and polymers with allylic chloride end groups Friedel-Crafts catalys May 18, 1993
Hydrocarbons and polymers thereof, of the structure (I)where R is a hydrocarbon radical, are prepared by reacting corresponding starting materials which contain chlorine bonded to tertiary carbon, of the structurewith from 1 to 10 moles of butadiene in the presence of a Friedel-Crafts ca
5189099 Thermoplastic molding materials based on polyesters and polyphenylene ethers February 23, 1993
Thermoplastic molding materials containA) from 5 to 94.9% by weight of a polyester,B) from 5 to 94.9% by weight of a polyphenylene ether,C) from 0.1 to 50% by weight of a homopolymer or copolymer obtainable by anionic polymerization of a vinylaromatic compound or a diene, or a mixture thereo
5171800 Anionic polymerization with bifunctional initiators December 15, 1992
An organic compound of an alkali metal, of the formula I ##STR1## which is obtained by reaction of an appropriate diarylethylene of the formula II with an alkali metal (M), especially lithium, ##STR2## where Ar.sup.1 and Ar.sup.2 are identical or different aryl or hetaryl rad
5166286 Polymers having terminal halogen atoms November 24, 1992
Polymers having terminal halogen atoms and consisting of cationically polymerizable, olefinically unsaturated monomers are obtainable by polymerization using an initiator system comprising a halogen-containing Lewis acid and a 3-membered to 8-membered cyclic ether.
5122573 Preparation of polymers having tertiary chloride end groups June 16, 1992
A process for the preparation of polymers of isobutene having tertiary chloride groups by reaction of appropriate polymers which have been prepared by cationic polymerization of isobutene with hydrogen chloride.
5115022 Thermoplastics of polyalkylene terephthalates impact modified with functionalized polymers and u May 19, 1992
Impact modified thermoplastic blends of components A, B and optionally C, consisting of:A) from 99 to 60 percent by weight of a polymeric rigid matrix consisting of polybutylene terephthalate or polyethylene terephthalateB) from 1 to 40 percent by weight of a polymeric flexibilizing componen
5081251 Stilbene compounds use in anionic polymerization January 14, 1992
Stilbene compounds of the general formula Ia, Ib or Icwhere Ar.sup.1 to Ar.sup.4 are identical or different aromatic or quasi-aromatic radicals and n is from 0 to 20 and where either at least one of the radicals R.sup.1 to R.sup.6 or R.sup.9 is hydrocarbon-solubilizing alkyl, alkoxy, dia
5064907 Polymers with functional groups November 12, 1991
Modified homopolymer, random copolymers and/or block copolymers of aromatic vinyls and/or dienes contain functional groups of the general formula (I): ##STR1## where N is nitrogen, O is oxygen, Y is a substituted or unsubstituted bridge which besides carbon additionally contains N- o
5059645 Thermoplastic molding materials based on polyphenylene ethers October 22, 1991
Thermoplastic molding materials containa) from 20 to 80 parts by weight of a polyphenylene ether,b) from 1 to 20 parts by weight of a block copolymer of the general formula A--B--A' consisting of two polyvinylaromatic blocks A and A' and a partially hydrogenated rubber block B,c) from 0 to 7
5055527 Thermoplastics impact modified with functionalized polymers and use thereof for producing moldin October 8, 1991
Impact modified thermoplastic blends of components A, B and optionally C, consisting of:A) from 99 to 60 percent by weight of a polymeric rigid matrix consisting ofa1) 60-99.5 percent by weight of an aromatic vinyl compound present as copolymerized units,a2) 0.5-20 percent by weight of a
5053561 Method of isolating trans-1,1,4,4-tetraalkyl-2-butene-1,4-diols October 1, 1991
A method of isolating trans-1,1,4,4-tetraalkyl-2-butene-1,4-diols of formula I ##STR1## in which R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are the same or different and denote C.sub.1 - to C.sub.5 -alkyl, from mixtures thereof with their cis-isomers, wherein the trans-isomer is separ
5053462 Modified polyisobutene October 1, 1991
A modified polyisobutene has the general formula I ##STR1## where R.sup.1 is an olefinically unsaturated divalent radical, R.sup.2 is one of the radicals --CH.sub.2 --C(.dbd.CH.sub.2)--CH.sub.2 -- or --CH.sub.2 --C(CH.sub.3).dbd.CH-- or m and n are each a degree of polymerization
5053458 Thermoplastic molding materials October 1, 1991
Thermoplastic molding materials contain, as essential components,A) from 5 to 94% by weight of a polyamide,B) from 5 to 94% by weight of a polyphenylene ether,C) from 1 to 20% by weight of a partially hydrogenated PQP' block copolymer, where.alpha.) the blocks P and P' consist of vinylaromatic m
5036130 Transparent thermoplastic molding material, its preparation and its use July 30, 1991
A transparent thermoplastic molding material contains, based on A+B,A: from 5 to 95% by weight of polystyrene andB; from 95 to 5% by weight of a nonelastomeric star block copolymer which is composed of, based on B, b.sub.1 from 60 to 95% by weight of styrene and b.sub.2 from 5 to 40% by weig
5003010 Salts of polyvalent cations with block polymers of vinylaromatics and conjugated dienes March 26, 1991
Block polymers of vinylaromatics and conjugated dienes which posses acidic terminal groups and are in the form of salts which contain divalent or polyvalent metal cations or cation complexes. A process for the preparation of such salts of block polymers containing acid groups, and th
4988773 Homopolymers or block copolymers of vinylaromatics and/or dienes with ammonium groups, and prepa January 29, 1991
Homopolymers or block copolymers of vinylaromatics and/or dienes and hydrogenated derivatives thereof, which contain end groups of the general formula (I):where A is a substituted or unsubstituted bridge which, in addition to carbon, may contain nitrogen or oxygen, X is 0 or 1, S is an i
4985503 Preparation of impact-resistant poly(alkyl)styrene January 15, 1991
Process for preparing impact-resistant translucent rubber-modified polystyrene by polymerizing compounds of the styrene class in the presence of a rubber containing thiol groups.
4972023 Polymers modified with terminal acid groups and the preparation and use of these polymers November 20, 1990
Homopolymers, copolymers or block copolymers obtained from vinylaromatics and/or conjugated dienes and functionally modified at chain ends via amide groups with terminal acid groups or salts thereof, and hydrogenation products of these polymers, which contain salts of functional groups o
4929786 Preparation of 1-aryl-1-alkenes May 29, 1990
Preparation of 1-aryl-1-alkenes by dehydration of 1-aryl-1-alkanols in the presence of a substance promoting elimination of water, the substance being a triester of phosphorous acid in which at least one of the radicals is an aryl group.The products are suitable as, inter al., initiators
4921775 Elements having layers containing mixtures which can be crosslinked by photopolymerization May 1, 1990
Mixtures which can be crosslinked by photopolymerization and are based on binders, photopolymerizable monomers which are compatible with these, photoinitiators and thermal polymerization inhibitors contain, as the binder, polymers of the formula I ##STR1## where Pol is a radical
4908414 Preparation of impact-resistant poly(alkyl)styrene March 13, 1990
Impact-resistant translucent rubber-modified polystyrene is produced by polymerizing compounds from the class of the styrenes in the presence of an elastomeric polymer which contains thiol groups.
4891410 Butadiene/sytrene block copolymers having an asymmetric structure, their preparation and their u January 2, 1990
In block copolymers of the general formula A--B--A' which have a molecular weight of less than 300,000 and consist of from 18 to 40% by weight of a vinylaromatic hydrocarbon and from 60 to 82% by weight of one or more partially or completely hydrogenated hydrocarbons and in which A and A
4861742 Bifunctional alkali metal compounds, preparation and use thereof as polymerization initiators August 29, 1989
Bifunctional initiators for anionic polymerization are prepared by reacting an alkenylaromatic compound of the general formula I ##STR1## where Ar is aromatic hydrocarbyl which may be substituted by alkyl or another group inert toward organoalkali metal compounds and may contain
4839434 Preparation of homo- and copolymers having terminal mercapto groups and their use June 13, 1989
Homo- or copolymers which have terminal mercapto groups, are composed of one or more monomers from the group consisting of butadiene, isoprene and styrene and are obtained by anionic polymerization of one or more of the stated monomers in the presence of one or more organolithium compoun
4835221 Salts of polyvalent cations of polymers of conjugated dienes May 30, 1989
Polymers and copolymers of conjugated dienes and aromatic vinyl compound which have a carboxyl end group and are present as salts, the salts containing metal cations or metal cation complexes which are bivalent or polyvallent and also a process for preparing such salts of polymers which
4835220 Transparent, impact-resistant styrene block polymers and their preparation May 30, 1989
Block polymers of vinylaromatic compounds and conjugated dienes which possess acidic terminal groups, are present in the form of lithium salts and form an aluminum complex. A process for the preparation of such complexes and the use of these block polymer complexes as molding materia
4822945 Preparation of decene oligomers and use thereof as lubricating oils April 18, 1989
Decene oligomers useful with or without hydrogenation as basis for synthetic lubricating oils are prepared by oligomerizing decene-1 in the presence of an alkylaluminum chloride catalyst and an alkyl halide cocatalyst, in a first reaction stage the decene-1 being mixed with the catal
4822530 Preparation of polyfunctional initiators for anionic polymerization, oligomeric polyfunctional i April 18, 1989
Oligomeric polyfunctional initiators for anionic polymerization of dienes and/or alkenylaromatics are prepared by a process in which a mixture of dialkenylaromatics and alkenylaromatics in a molar ratio of from 1:4 to 1:100, in an inert solvent, is run, at from 25.degree. to 100.degree.
4816520 Terminally functionalized polymers and preparation thereof March 28, 1989
The terminally functionalized polymers are prepared from living polymers obtained by anionic polymerization of olefinically unsaturated monomers by reacting the living polymers first with capping reagents comprising nitrogen compounds of the general formulae I to VII: ##STR1## wh
4791174 Polymers containing amino groups, their preparation and their use December 13, 1988
Homo- co- and/or block polymers which are modified with amino functional groups, are obtained from vinylaromatics and/or dienes and contain functional groups of the formulae (I) to (VI) ##STR1## where N is nitrogen, R.sup.1 and R.sup.4 are each hydrogen, alkyl, cycloalkyl or aryl
4786736 Preparation of diaziridines and products therefrom November 22, 1988
Process for preparing N,N'-dialkyldiaziridines or bicyclic diaziridines of the general formula I or II: ##STR1## where R.sup.1 and R.sup.2 are each alkyl or aryl, A is a substituted or unsubstituted one-membered carbon bridge and B is a substituted or unsubstituted three-membered
4753991 Polymers containing amino groups, and their preparation June 28, 1988
Homopolymers, copolymers and/or block copolymers which are obtained from vinylaromatics and/or dienes, are modified with functional amino groups and contain functional groups of the formula (I) or (II) ##STR1## where N is nitrogen, R.sup.1 and R.sup.2 are each alkyl or aryl, A is an
4663406 Catalyst systems for the cationic polymerization of isobutylene May 5, 1987
Isobutylene polymers are prepared by polymerizing the monomers at from 0.2 to 20 bar and from -130.degree. and +60.degree. C. in the presence of from 0.01 to 20 mmol of a boron halide catalyst system which contains as cocatalyst a carboxylic anhydride or carbonyl halide, preferably an
4602068 Chlorination of polymers July 22, 1986
Solid organic polymers are chlorinated with chlorine to give chlorinated polymers in the presence of a solvent which contains from 20 to 100% by weight of phosgene and in which the polymer is dissolved or suspended, at or below the boiling point of the mixture of chlorine and solvent, by
4599433 Reaction of olefins with maleic anhydride July 8, 1986
Olefinically unsaturated hydrocarbons, in particular dimeric or polymeric isobutene derivatives, which have a mean number average molecular weight M.sub.n of from 100 to 3000, are reacted with maleic anhydride in a molar ratio of maleic anhydride to olefin of from 0.2 to 3.0, in the pres
4587307 Quality of isobutene polymers in reactions with maleic anhydride May 6, 1986
The processing properties of isobutene polymers when reacted with maleic anhydride are improved by a method in which these polymers are brought into contact, for an effective period,with aluminum oxide and/or a completely or partially hydrated aluminum oxide at 50.degree.-280.degree. C.,
4558104 Continuous preparation of isobutylene polymers December 10, 1985
Isobutylene polymers are prepared continuously, in aliphatic C.sub.3 -C.sub.6 -hydrocarbons in the presence of soluble cationic polymerization initiators and coinitiators at from -40.degree. to 40.degree. C. and under from 0.01 to 10 bar, and the solvents and monomers vaporized during th
4526927 Thermoplastic molding materials July 2, 1985
A thermoplastic molding material contains a styrene polymer, a polyphenylene ether and, as a component for improving the impact strength, a block copolymer obtained by reacting an ethylene copolymer with an active polymeric anion.
4296222 Manufacture of poly-.alpha.-olefins October 20, 1981
A process for the manufacture of poly-.alpha.-olefins by polymerizing .alpha.-olefins by means of a catalyst system comprising (1) a titanium-containing component obtained from (1.1) a compound of the formula TiCl.sub.3.1/3AlCl.sub.3 and (1.2) an organic electron donor, containing ph
4282341 Manufacture of homopolymers and copolymers of .alpha.-monoolefins August 4, 1981
A process for the manufacture of homopolymers and copolymers of .alpha.-monoolefins by polymerizing the monomer or monomers at relatively low temperatures under relatively low pressures by means of a Ziegler-Natta catalyst comprising (I) a titanium chloride component and (II) an alum
4208497 Manufacture of homopolymers and copolymers of .alpha.-monoolefins June 17, 1980
A process for the manufacture of homopolymers and copolymers of .alpha.-monoolefins by polymerizing the monomer or monomers at relatively low temperatures under relatively low pressures by means of a Ziegler-Natta catalyst comprising (I) a titanium trichloride component and (II) an a
4207409 Catalytic hydrogenation of diolefin polymers June 10, 1980
In the hydrogenation of polymers or copolymers synthesized from dienes, or containing diene hydrocarbons, which is as a rule carried out in an organic solvent using hydrogen in the presence of conventional complex hydrogenation catalysts based on metals of sub-group 8 of the periodic
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