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Browse by: INVENTOR PATENT HOLDER PATENT NUMBER DATE
 
 
Inventor:
Stevens; James C.
Address:
Richmond, TX
No. of patents:
49
Patents:




Patent Number Title Of Patent Date Issued
7553917 Technique for selecting polymerization modifiers cross reference statement June 30, 2009
A combinatorial method for identifying a catalyst composition for use in the homogeneous addition polymerization of an olefin monomers, said catalyst composition comprising a transition metal compound, a cocatalyst and a polymerization modifier, as well as catalyst compositions and i
7344775 Isotactic propylene copolymer fibers, their preparation and use March 18, 2008
Fibers comprising a propylene homopolymer or a copolymer of propylene and at least one of ethylene and one or more unsaturated comonomers exhibit desirable properties. The homopolymers are characterized as having .sup.13C NMR peaks corresponding to a regio-error at about 14.6 and about
7300983 High melt strength polymers and method of making same November 27, 2007
A polymer composition that has a backbone chain; and a plurality of long chain branches connected to the backbone is described. The polymer composition also has a value of .sup.2g'.sub.LCB-.sup.1g'.sub.LCB that is less than about 0.22, where .sup.1g'.sub.LCB is the long chain branching
7271221 Method of making interpolymers and products made therefrom September 18, 2007
Olefin polymers having a melt strength of about 5cN at 190 .degree. C., and when made into a film have a CD shrink of at least 20%. Some of the polymers have a comb-like structure with at least 0.3 long-chain branches per 1000 carbon atoms are disclosed. Some compositions described herei
7250471 Impact resistance polymer blends of crystalline polypropylene and partially crystalline, low mol July 31, 2007
Polymer blends that exhibit good impact resistance comprise a crystalline polypropylene matrix and a partly crystalline copolymer impact modifier with a molecular weight lower than that of the matrix polymer. The matrix polymer can comprise any crystalline propylene homo- or copolymer. T
7250470 Crystallization of polypropylene using a semi-crystalline, branched or coupled nucleating agent July 31, 2007
A method of nucleating a propylene homo- or copolymer, the method comprising contacting the propylene polymer with a semi-crystalline branched or coupled polymeric nucleating agent under nucleation conditions. In one embodiment, the propylene homopolymer is characterized as having .s
7238759 Isotactic propylene copolymers, their preparation and use July 3, 2007
Unique copolymers comprising propylene, ethylene and/or one or more unsaturated comonomers are characterized as having: at least one, preferably more than one, of the following properties: (i) .sup.13C NMR peaks corresponding to a regio-error at about 14.6 and about 15.7 ppm, the pea
7214638 Olefin polymerization catalyst composition comprising group 13 amide derivatives May 8, 2007
Catalyst compositions that are highly tolerant of catalyst poisons for use in addition polymerizations comprising a catalytic derivative of a Group 4 metal complex, a cocatalyst, and a Group 13 metal amide compound.
7199203 Isotactic propylene copolymer fibers, their preparation and use April 3, 2007
Fibers comprising a propylene homopolymer or a copolymer of propylene and at least one of ethylene and one or more unsaturated comonomers exhibit desirable properties. The homopolymers are characterized as having .sup.13C NMR peaks corresponding to a regio-error at about 14.6 and about
7148305 Method of making interpolymers and products made therefrom December 12, 2006
Olefin polymers having a comb-like structure with at least 0.3 long-chain branches per 1000 carbon atoms are disclosed. Some compositions have a melt strength of about 5 cN at 190.degree. C., and when made into a film have a CD shrink of at least 20%. Some compositions described herein
7109269 Impact resistant polymer blends of crystalline polypropylene and partially crystalline, low mole September 19, 2006
Polymer blends that exhibit good impact resistance comprise a crystalline polypropylene matrix and a partly crystalline copolymer impact modifier with a molecular weight lower than that of the matrix polymer. The matrix polymer can comprise any crystalline propylene homo- or copolymer. T
7060754 Crystallization of polypropylene using a semi-crystalline, branched or coupled nucleating agent June 13, 2006
A method of nucleating a propylene homo- or copolymer, the method comprising contacting the propylene polymer with a semi-crystalline branched or coupled polymeric nucleating agent under nucleation conditions. In one embodiment, the propylene homopolymer is characterized as having .s
6960635 Isotactic propylene copolymers, their preparation and use November 1, 2005
Unique copolymers comprising propylene, ethylene and/or one or more unsaturated comonomers are characterized as having: at least one, preferably more than one, of the following properties: (i) .sup.13 C NMR peaks corresponding to a regio-error at about 14.6 and about 15.7 ppm, the pe
6953764 High activity olefin polymerization catalyst and process October 11, 2005
Group 4 metal complexes useful as addition polymerization catalysts of the formula: ##STR1##wherein G.sup.1 is a group containing from 1 to 40 atoms not counting hydrogen; T is a divalent bridging group of from 10 to 30 atoms not counting hydrogen, selected from mono- or di-aryl-su
6943215 Impact resistant polymer blends of crystalline polypropylene and partially crystalline, low mole September 13, 2005
Polymer blends that exhibit good impact resistance comprise a crystalline polypropylene matrix and a partly crystalline copolymer impact modifier with a molecular weight lower than that of the matrix polymer. The matrix polymer can comprise any crystalline propylene homo- or copolymer. T
6927256 Crystallization of polypropylene using a semi-crystalline, branched or coupled nucleating agent August 9, 2005
A method of nucleating a propylene homo- or copolymer, the method comprising contacting the propylene polymer with a semi-crystalline branched or coupled polymeric nucleating agent under nucleation conditions. In one embodiment, the propylene homopolymer is characterized as having .s
6924342 Method of making interpolymers and products made therefrom August 2, 2005
A polymerization process comprises contacting one or more olefinic comonomers in the presence of at least a high molecular weight catalyst and at least a low molecular weight catalyst in a single reactor, and effectuating the polymerization of the olefinic comonomers in the reactor t
6906160 Isotactic propylene copolymer fibers, their preparation and use June 14, 2005
Fibers comprising a propylene homopolymer or a copolymer of propylene and at least one of ethylene and one or more unsaturated comonomers exhibit desirable properties. The homopolymers are characterized as having .sup.13 C NMR peaks corresponding to a regio-error at about 14.6 and about
6875816 High melt strength polymers and method of making same April 5, 2005
A polymer composition comprises: (a) a high molecular weight, branched component; and (b) a low molecular weight, branched component. Some polymer compositions are characterized by a substantial absent of amyl or methyl branches and a melt strength (MS) that satisfies the following r
6844399 Sulfonated substantially random interpolymers, blends therewith and articles made therefrom January 18, 2005
Sulfonated substantially random interpolymers made from monomer components comprise from 1 to 65 mole percent of (a) at least one vinyl or vinylidene aromatic monomer, or (b) at least one hindered aliphatic or cycloaliphatic vinylidene monomer, or (c) a combination of at least one vinyl
6780954 Elastic substantially linear ethylene polymers August 24, 2004
Elastic ethylene polymers are disclosed which have processability similar to highly branched low density polyethylene (LDPE), but the strength and toughness of linear low density polyethylene (LLDPE). The polymers have processing indices (PI's) less than or equal to 70 percent of those o
6696379 Supported modified alumoxane catalyst activator February 24, 2004
A supported catalyst composition comprising: A1) a mixture of aluminum containing Lewis acids of the formulas:
6538080 Gas phase polymerization of olefins March 25, 2003
A gas phase fluidized bed process is described for producing ethylene polymers having improved processability and an MWD of less than about 2.9. Multiple reactors in series or parallel may be used to produce in-situ blended polymers. Each reactor can separately have a constrained geometr
6534612 Elastic substantially linear ethylene polymers March 18, 2003
Elastic ethylene polymers are disclosed which have processability similar to highly branched low density polyethylene (LDPE), but the strength and toughness of linear low density polyethylene (LDPE). The polymers have processing indices (PI's) less than or equal to 70 percent of those of
6512049 Sulfonated substantially random interpolymers, blends therewith and articles made therefrom January 28, 2003
Sulfonated substantially random interpolymers made from monomer components comprise from 1 to 65 mole percent of (a) at least one vinyl or vinylidene aromatic monomer, or (b) at least one hindered aliphatic or cycloaliphatic vinylidene monomer, or (c) a combination of at least one vinyl
6506867 Elastic substantially linear ethylene polymers January 14, 2003
Elastic ethylene polymers are disclosed which have processability similar to highly branched low density polyethylene (LDPE), but the strength and toughness of linear low density polyethylene (LLDPE). The polymers have processing indices (PI's) less than or equal to 70 percent of those o
6479594 Sulfonated substantially random interpolymers, blends therewith and articles made therefrom November 12, 2002
Sulfonated substantially random interpolymers made from monomer components comprise from 1 to 65 mole percent of (a) at least one vinyl or vinylidene aromatic monomer, or (b) at least one hindered aliphatic or cycloaliphatic vinylidene monomer, or (c) a combination of at least one vinyl
6465384 Biscyclopentadienyl diene complexes October 15, 2002
Biscyclopentadienyl, Group 4 transition metal complexes formed with conjugated dienes wherein the diene is bound to the transition metal either in the form of a .sigma.-complex or a .pi.-complex in combination with strong Lewis acids, Bronsted acid salts, carbenium ion salts, salts c
6420507 Olefin polymers prepared with substituted indenyl containing metal complexes July 16, 2002
The subject invention is directed to an olefin polymer produced by polymerizing at least one .alpha.-olefin in the presence of a Group 4 metal complex comprising an indenyl group substituted in the 2 or 3 position with at least one group selected from hydrocarbyl, perfluoro-substitut
6136937 Elastic substantially linear ethylene polymers October 24, 2000
Elastic ethylene polymers are disclosed which have processability similar to highly branched low density polyethylene (LDPE), but the strength and toughness of linear low density polyethylene (LLDPE). The polymers have processing indices (PI's) less than or equal to 70 percent of those o
6107374 Asphalt modified with olefin/vinylidene aromatic monomer interpolymers August 22, 2000
Bitumens can be blended with interpolymers prepared from least one olefin and at least one vinyl or vinylidene aromatic monomer and, optionally, at least one diene. The interpolymers prepared from monomers containing a diene are new compositions of matter. When the interpolymers prepared
6087447 Blends of substantially random interpolymers with vinyl or vinylidene aromatic polymers July 11, 2000
Blends of polymeric materials comprising (A) from about 1 to about 99 weight percent of at least one interpolymer containing (1) from about 1 to about 65 mole percent of (a) at least one vinylidene aromatic monomer, or (b) at least one hindered aliphatic vinylidene monomer, or (c) a
6075077 Asphalt, bitumen, and adhesive compositions June 13, 2000
The subject invention is directed to a composition comprising a polymer, comprising in polymerized form ethylene and at least one additional polymerizable monomer, prepared by polymerizing ethylene and said at least one addition polymerizable monomer in the presence of a catalyst com
6074977 Olefin addition polymerization catalyst composition June 13, 2000
Catalyst compositions that are highly tolerant of catalyst poisons comprising a cationic or zwitterionic Group 4 metal complex of the constrained geometry type and an organoaluminum hydrocarbyloxide compound according to the formula R.sup.1.sub.2 Al(OR.sup.2),wherein R.sup.1 and R.sup.2
6025448 Gas phase polymerization of olefins February 15, 2000
A gas phase fluidized bed process is described for producing ethylene polymers having improved processability and an MWD of less than about 2.9. Multiple reactors in series or parallel may be used to produce in-situ blended polymers. Each reactor can separately have a constrained geometr
6017842 Olefin polymerization catalyst composition comprising group 13 compound January 25, 2000
Catalyst compositions that are highly tolerant of catalyst poisons comprising a catalytic derivative of a Group 4 metallocene metal complex and an Group 13 metal compound according to the formula R.sup.1.sub.2 M"(NR.sup.2.sub.2),wherein R.sup.1 and R.sup.2 independently each occurrence i
6015868 Substituted indenyl containing metal complexes and olefin polymerization process January 18, 2000
Group 4 metal complexes comprising an indenyl group substituted in the 2 or 3 position with at least one group selected from hydrocarbyl, fluoro-substituted hydrocarbyl, hydrocarbyloxy-substituted hydrocarbyl, dialkylamino-substituted hydroacrbyl, silyl, germyl and mixtures thereof,
6013819 Reduced oxidaton state group 4 metal complexes, addition polymerization catalysts, and polymeriz January 11, 2000
Metal complexes having constrained geometry and a process for preparation thereof, addition polymerization catalysts formed therefrom, processes for preparation of such addition polymerization catalysts, methods of use, and novel polymers formed thereby, including ElPE resins and pseudo-
5986028 Elastic substantially linear ethlene polymers November 16, 1999
A continuous polymerization process of preparing ethylene polymers containing less than about 20 ppm aluminum, and having processability similar to highly branched low density polyethylene (LDPE), but the strength and toughness of linear low density polyethylene (LLDPE). The polymers
5972822 Biscyclopentadienyldiene complex containing addition polymerization catalysts October 26, 1999
Catalysts for polymerizing olefins, diolefins and/or acetylenically unsaturated monomers comprising biscyclopentadienyl, Group 4 transition metal complexes formed with conjugated dienes wherein the diene is bound to the transition metal either in the form of a .sigma.-complex or a .p
5883204 Solution polymerization process with dispersed catalyst activator March 16, 1999
A dispersible ionic catalyst activator, comprising an insoluble substrate material having a correlated settling rate less than 0.03 cm/sec, and from 0.001 to 10 mmol/g of an ionic catalyst activator deposited thereon which is particularly adapted for use in a continuous, solution polymer
5783638 Elastic substantially linear ethylene polymers July 21, 1998
Elastic ethylene polymers are disclosed which have processability similar to highly branched low density polyethylene (LDPE), but the strength and toughness of linear low density polyethylene (LLDPE). The polymers have processing indices (PI's) less than or equal to 70 percent of those o
5770538 Group 4 metal diene complexes and addition polymerization catalysts therefrom June 23, 1998
Novel Group 4 metal complexes containing one and only one cyclic delocalized, anionic, .pi.-bonded group wherein the metal is in the +4 formal oxidation state and having a bridged ligand structure, also referred to as constrained geometry complexes and a conjugated diene divalent ani
5624878 Titanium (II) or zirconium (II) complexes and addition polymerization catalysts therefrom April 29, 1997
Novel catalytic derivatives of titanium or zirconium complexes containing one and only one cyclic delocalized, anionic, .PI.-bonded group wherein the metal is in the +2 formal oxidation state and having a bridged ligand structure and an activating cocatalyst are useful as catalysts for
5616664 Polymerization process with biscyclopentadienyl diene complex containing catalysts April 1, 1997
Olefins are polymerized by the use of catalysts comprising biscyclopentadienyl, Group 4 transition metal complexes formed with conjugated dienes wherein the diene is bound to the transition metal either in the form of a .sigma.-complex or a .pi.-complex in combination with activating
5556928 Titanium (II) or Zirconium (II) complexes and addition polymerization catalysts therefrom September 17, 1996
A process for polymerizing olefins, diolefins and/or acetylenically unsaturated monomers using novel catalyst compositions comprising titanium or zirconium complexes containing one and only one cyclic delocalized, anionic, .pi.-bonded group wherein the metal is in the +2 formal oxidation
5539068 Group 4, metal-conjugated diene metallocyclopentene complexes, and addition polymerization catal July 23, 1996
Novel Group 4 metal complexes containing one and only one cyclic delocalized, anionic, .pi.-bonded group wherein the metal is in the +4 formal oxidation state and having a bridged ligand structure, also referred to as constrained geometry complexes and a conjugated diene divalent ani
5486632 Group 4 metal diene complexes and addition polymerization catalysts therefrom January 23, 1996
Novel Group 4 metal complexes containing one and only one cyclic delocalized, anionic, .pi.-bonded group wherein the metal is in the +4 formal oxidation state and having a bridged ligand structure, also referred to as constrained geometry complexes and a conjugated diene divalent ani
5460818 Compatibilized blend of olefinic polymers and monovinylidene aromatic polymers October 24, 1995
A polymer blend composition comprising:(a) from 0.5 to 99 percent by weight, based on the total weight of (a), (b), and (c), of an aliphatic .alpha.-olefin homopolymer or interpolymer, or an interpolymer of an .alpha.-olefin and a non-aromatic monomer interpolymerizable therewith;(b) fro


 
 
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