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Browse by: INVENTOR PATENT HOLDER PATENT NUMBER DATE
 
 
Inventor:
Marks; Tobin J.
Address:
Evanston, IL
No. of patents:
78
Patents:


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Patent Number Title Of Patent Date Issued
7605394 Siloxane-polymer dielectric compositions and related organic field-effect transistors October 20, 2009
Dielectric compositions comprising siloxane and polymeric components, as can be used in a range of transistor and related device configurations.
7605225 Silole-based polymers and semiconductor materials prepared from the same October 20, 2009
The present teachings provide silole-based polymers that can be used as p-type semiconductors. More specifically, the present teachings provide polymers that include a repeating unit of Formula I: ##STR00001## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, Z, x, and x'
7569693 Naphthalene-based semiconductor materials and methods of preparing and use thereof August 4, 2009
Provided are mono- and diimide naphthalene compounds for use in the fabrication of various device structures. In some embodiments, the naphthalene core of these compounds are mono-, di-, or tetra-substituted with cyano group(s) or other electron-withdrawing substituents or moieties.
7528176 Carbonyl-functionalized thiophene compounds and related device structures May 5, 2009
Carbonyl-functionalized oligo/polythiophene compounds, and related semiconductor components and related device structures.
7476345 Layer by layer self-assembly of large response molecular electro-optic materials by a desilylati January 13, 2009
The preparation of robust, thin film materials with large second-order optical nonlinearities through the covalent self-assembly of chromophoric compositions and innovative use of silyl chemistry.
7449509 Hole transport layer compositions and related diode devices November 11, 2008
Hole transport layer compositions comprising a silylated aryl amine and a polymeric component, to enhance performance of an associated electroluminescent device.
7374702 n-Type thiophene semiconductors May 20, 2008
The new fluorocarbon-functionalized and/or heterocycle-modified polythiophenes, in particular, .alpha.,.omega.-diperfluorohexylsexithiophene DFH-6T can be straightforwardly prepared in high yield and purity. Introduction of such modifications to a thiophene core affords enhanced ther
7291293 Vapor deposited electro-optic films self-assembled through hydrogen bonding November 6, 2007
The present invention introduces a novel route toward microstructural orientation into organic films, using multiple hydrogen-bonding to self-assemble chromophore molecules into electro-optic films in a net polar orientation. High-quality, thick films (up to micrometers) with molecul
7160965 Cyclopentadienyl-containing low-valent early transition metal olefin polymerization catalysts January 9, 2007
A catalyst system useful to polymerize and co-polymerize polar and non-polar olefin monomers is formed by in situ reduction with a reducing agent of a catalyst precursor comprising {Cp*MRR'.sub.n}.sup.+{A}.sup.- wherein Cp* is a cyclopentadienyl or substituted cyclopentadienyl moiety;
7119158 Cyclopentadienyl-containing low-valent early transition metal olefin polymerization catalysts October 10, 2006
A catalyst system useful to polymerize and co-polymerize polar and non-polar olefin monomers is formed by in situ reduction with a reducing agent of a catalyst precursor comprising {Cp*MRR'.sub.n}.sup.+{A}.sup.- wherein Cp* is a cyclopentadienyl or substituted cyclopentadienyl moiety;
7094121 Organic light-emitting diodes and methods for assembly and emission control August 22, 2006
New organic light-emitting diodes and related electroluminescent devices and methods for fabrication, using siloxane self-assembly techniques.
6991749 n-Type thiophene semiconductors January 31, 2006
The new fluorocarbon-functionalized and/or heterocycle-modified polythiophenes, in particular, .alpha.,.omega.-diperfluorohexylsexithioph- ene DFH-6T can be straightforwardly prepared in high yield and purity. Introduction of such modifications to a thiophene core affords enhanced the
6939625 Organic light-emitting diodes and methods for assembly and enhanced charge injection September 6, 2005
New organic light-emitting diodes and related electroluminescent devices and methods for fabrication, using siloxane self-assembly techniques.
6855274 Layer by layer self-assembly of large response molecular electro-optic materials by a desilylati February 15, 2005
The preparation of robust, thin film materials with large second-order optical nonlinearities through the covalent self-assembly of chromophoric compositions and innovative use of silyl chemistry.
6747112 Cyclopentadienyl-containing low-valent early transition metal olefin polymerization catalysts June 8, 2004
A catalyst system useful to polymerize and co-polymerize polar and non-polar olefin monomers is formed by in situ reduction with a reducing agent of a catalyst precursor comprisingwherein Cp* is a cyclopentadienyl or substituted cyclopentadienyl moiety; M is an early transition metal; R
6670299 Cyclopentadienyl-containing low-valent early transition metal olefin polymerization catalysts December 30, 2003
A catalyst system useful to polymerize and co-polymerize polar and non-polar olefin monomers is formed by in situ reduction with a reducing agent of a catalyst precursor comprisingwherein Cp* is a cyclopentadienyl or substituted cyclopentadienyl moiety; M is an early transition metal; R
6635597 Perfluoronaphthyl substituted boron containing catalyst activator October 21, 2003
A catalyst activator particularly adapted for use in the activation of metal complexes of metals of Group 3-10 for polymerization of ethylenically unsaturated polymerizable monomers, especially olefins, comprising a neutral (Lewis acid) or charge separated (cation/anion pair) compris
6608323 n-type thiophene semiconductors August 19, 2003
The new fluorocarbon-functionalized polythiophenes, in particular, .alpha.,.omega.-diperfluorohexylsexithiophene DFH-6T (1) can be straightforwardly prepared in high yield and purified by gradient sublimation. Introduction of perfluorocarbon chains on the thiophene core affords enhan
6586763 Organic light-emitting diodes and methods for assembly and emission control July 1, 2003
New organic light-emitting diodes and related electroluminescent devices and methods for fabrication, using siloxane self-assembly techniques.
6585914 N-type thiophene semiconductors July 1, 2003
The new fluorocarbon-functionalized and/or heterocycle-modified polythiophenes, in particular, .alpha.,.omega.-diperfluorohexylsexithiophene DFH-6T can be straightforwardly prepared in high yield and purity. Introduction of such modifications to a thiophene core affords enhanced ther
6549685 High-response electro-optic modulator based on an intrinsically acentric, layer-by-layer self-as April 15, 2003
A new electro-optic (EO) phase modulator constructed from a combination of a low-loss passive polymer waveguide and a self-assembled chromophore superlattice (SAS) with an intrinsically polar microstructure. In contrast to typical polymer-based modulators, the present invention utilizes
6544922 Cyclopentadienyl-containing low-valent early transition metal olefin polymerization catalysts April 8, 2003
A catalyst system useful to polymerize and co-polymerize polar and non-polar olefin monomers is formed by in situ reduction with a reducing agent of a catalyst precursor comprisingwherein Cp* is a cyclopentadienyl or substituted cyclopentadienyl moiety; M is an early transition metal; R
6403733 Organo-Lewis acid as cocatalyst for cationic homogeneous Ziegler-Natta olefin polymerizations June 11, 2002
Organo-Lewis acids of the formula BR'R".sub.2 wherein B is boron, R' is fluorinated biphenyl, and R" is a fluorinated phenyl, fluorinated biphenyl, or fluorinated polycyclic fused ring group, and cationic metallocene complexes formed therewith. Such complexes are useful as polymeriza
6403732 Organo-Lewis acids of enhanced utility, uses thereof, and products based thereon June 11, 2002
The organo-Lewis acids are novel triarylboranes which are are highly fluorinated. Triarylboranes of one such type contain at least one ring substituent other than fluorine. These organoboranes have a Lewis acid strength essentially equal to or greater than that of the corresponding o
6399221 Organic light-emitting diodes and methods for assembly and emission control June 4, 2002
New organic light-emitting diodes and related electroluminescent devices and methods for fabrication, using siloxane self-assembly techniques.
6388114 (Polyfluoroaryl) fluoroanions of aluminum, gallium, and indium of enhanced utility, uses thereof May 14, 2002
The (polyfluoroaryl)fluoroanions of aluminum, gallium, and indium are novel weakly coordinating anions which are highly fluorinated. (Polyfluoroaryl)fluoroanions of one such type contain at least one ring substituent other than fluorine. These (polyfluoroaryl)fluoroanions of aluminum
6291695 Organo-Lewis acids of enhanced utility, uses thereof, and products based thereon September 18, 2001
The organo-Lewis acids are novel triarylboranes which are highly fluorinated. Triarylboranes of one such type contain at least one ring substituent other than fluorine. These organoboranes have a Lewis acid strength essentially equal to or greater than that of the corresponding organ
6274752 Organo-Lewis acid as cocatalyst for cationic homogeneous Ziegler-Natta olefin polymerizations August 14, 2001
Organo-Lewis acids of the formula BR'R".sub.2 wherein B is boron, R' is fluorinated biphenyl, and R" is a fluorinated phenyl, fluorinated biphenyl, or fluorinated polycyclic fused ring group, and cationic metallocene complexes formed therewith. Such complexes are useful as polymeriza
6268445 Catalyst activator July 31, 2001
A catalyst activator particularly adapted for use in the activation of metal complexes of metals of Group 3-10 for polymerization of ethylenically unsaturated polymerizable monomers, especially olefins, comprising two Group 13 metal or metalloid atoms and a ligand structure including
6262200 (Polyfluoroaryl)fluoroanions of aluminum, gallium, and indium of enhanced utility, uses thereof, July 17, 2001
The (polyfluoroaryl)fluoroanions of aluminum, gallium, and indium are novel weakly coordinating anions which are are highly fluorinated. (Polyfluoroaryl)fluoroanions of one such type contain at least one ring substituent other than fluorine. These (polyfluoroaryl)fluoroanions of alum
6235918 Supported organometallic catalysts for hydrogenation and Olefin Polymerization May 22, 2001
Novel heterogeneous catalysts for the which hydrogenation of olefins and arenes with high conversion rates under ambient conditions and the polymerization of olefins have been developed. The catalysts are synthesized from Ziegler-type precatalysts by supporting them on sulfate-modifi
6229034 Synthesis and use of (perfluoroaryl) fluoro-aluminate anion May 8, 2001
A trityl perfluorophenyl alumninate such as tris(2,2',2"-nonafluorobiphenyl)-fluoroaluminate (PBA.sup..crclbar.) and its role as a cocatalyst in metallocene-mediated olefin polymerization is disclosed. Gallium and indium analogs are also disclosed, as are analogs with different anyl
6218332 (Polyfluoroaryl) fluoroanions of aluminum, gallium, and indium of enhanced utility, uses thereof April 17, 2001
The (polyfluoroaryl)fluoroanions of aluminum, gallium, and indium are novel weakly coordinating anions which are highly fluorinated. (Polyfluoroaryl)fluoroanions of one such type contain at least one ring substituent other than fluorine. These (polyfluoroaryl)fluoroanions of aluminum
6159890 Ruthenium-containing catalyst system for olefin metathesis December 12, 2000
A ruthenium-containing metathesis catalyst system which contains a ruthenium compound (A), a phosphorus, arsenic, or antimony compound (B), and a compound (C) containing at least one carbon-to-carbon triple bond. The mole ratio of compounds A:B:C is typically in the range of about 1.
6156692 Ruthenium-containing catalyst composition for olefin metathesis December 5, 2000
A ruthenium-containing metathesis catalyst system which contains a ruthenium compound (A), a phosphorus compound (B), and a compound (C) containing a carbon-to-carbon triple bond. The mole ratio of compounds A:B:C is typically in the range of about 1.0:0.01-100:0.01-100. The rutheniu
6153776 Bimetallic complexes and polymerization catalysts therefrom November 28, 2000
Group 3-6 or Lanthanide metal complexes possessing two metal centers, catalysts derived therefrom by combining the same with strong Lewis acids, Bronsted acid salts, salts containing a cationic oxidizing agent or subjected to bulk electrolysis in the presence of compatible, inert non
6130302 Synthesis and use of (polyfluoroaryl)fluoroanions of aluminum, gallium and indium October 10, 2000
Salts of (polyfluoroaryl)fluoroanions of aluminum, gallium, and indium are described. The (polyfluoroaryl)fluoroanions have the formula [ER'R"R'"F].sup..crclbar. wherein E is aluminum, gallium, or indium, wherein F is fluorine, and wherein R', R", and R'" is each a fluorinated pheny
6096905 Treatment of a composition comprising a trimethylolalkane bis-monolinear formal August 1, 2000
A process for treating a composition containing a substantial proportion of trimethylolpropane bis-monolinear formal (TMP-BMLF) or trimethylolethane bis-monolinear formal (TME-BMLF), e.g., a heavy ends residue obtained from the purification of a crude trimethylolpropane (TMP) or trimethy
6087460 Organo-Lewis acid as cocatalyst for cationic homogenous metallocene Ziegler-Natta olefin polymer July 11, 2000
The synthesis of the organo-Lewis acid perfluorobiphenylborane (PBB) and the activation of metallocenes for the formation of a variety of highly active homogeneous Ziegler-Natta metallocene olefin polymerization, copolymerization and ring-opening polymerization catalysts is described.
6077919 Silyl-terminated polymer and method for preparing silyl-terminated polyolefins June 20, 2000
There is disclosed a method for synthesizing polyolefins having a silyl group at one terminus, the method comprising reacting a monomer of an a-olefin (C.ltoreq.3.ltoreq.10) and a tetrasubstituted silyl radical in the presence of a metallocene catalyst.
6075103 Silyl-terminated polymer and method for preparing silyl-terminated polyolefins June 13, 2000
There is disclosed a method for synthesizing polyolefins having a silyl group at one terminus, the method comprising reacting a monomer of an .alpha.-olefin (C.ltoreq.3.ltoreq.10) and a tetrasubstituted silyl radical in the presence of a metallocene catalyst.
6040401 Saturated tricyclic ligand containing metal complexes and olefin polymerization process March 21, 2000
Bridged, group 4 Metal complexes useful as olefin polymerization catalyst components corresponding to the formula: L.sub.1 ZL.sub.2 MX.sub.m X'.sub.nor a dimer, solvated adduct, chelated derivative or mixture thereof, wherein:L.sub.1 is a partially saturated tricyclic group, especially
6033774 Self-assembled superlattices and waveguides prepared for use therewith March 7, 2000
One manner of construction of robust, thin film materials with large second-order optical nonlinearities is the covalent self-assembly of aligned arrays of high-.beta. molecular chromophores into multilayer superlattices. the dispersion of the large second harmonic generation (SHG) r
5939346 Catalyst system comprising an aryloxyaluminoxane containing an electron withdrawing group August 17, 1999
Aryloxyaluminoxanes containing the unit ##STR1## where R is unsubstituted or substituted aryl, such as phenyl or naphthyl, are useful as a cocatalysts in Ziegler-Natta and Kaminsky-type olefin polymerization catalysts. They can be formed by reaction of a source of water with an o
5856258 Phenolate constrained geometry polymerization catalyst and method for preparing January 5, 1999
The subject invention involves a method of preparing and the constrained geometry catalyst thereby prepared of the general formula Ar'R4(O)Ar"R'.sub.4 M(CH.sub.2 Ph).sub.2 where Ar' is a phenyl or naphthyl group; Ar" is a cyclopentadienyl or indenyl group, R and R' are H or alkyl sub
5856256 Organo-Lewis acid as cocatalyst for cationic homogeneous Ziegler-Natta olefin polymerizations January 5, 1999
A cationic metallocene complex with trisperfluorobiphenyl borate for use as a polymerization catalyst.
5854166 Synthesis and use of (perfluoroaryl) fluoro-aluminate anion December 29, 1998
A trityl perfluorophenyl alumninate such as tris(2,2',2"-nonafluorobiphenyl) fluoroaluminate (PBA.sup.-) and its role as a cocatalyst in metallocene-mediated olefin polymerization is disclosed.
5834100 Organic light-emitting dioddes and methods for assembly and emission control November 10, 1998
New organic light-emitting diodes and related electroluminescent devices and methods for fabrication, using siloxane self-assembly techniques.
5625106 Method for dimerizing an .alpha.-olefin April 29, 1997
A new class of olefin dimerization catalysts and an efficient method for their preparation is disclosed. B (C.sub.6 F.sub.5).sub.3 reacts quantitatively with Group 4 metallocene type catalysts to yield highly reactive cationic complexes as follows:(L.sub.2 MR.sup.2).sup.+ X.sup.- whereL
5591815 Zirconium and hafnium-catalyzed polymerization of methylenecyclopropane January 7, 1997
A polymer having a repeating unit of ##STR1## and a method for preparing it through Zr-catalyzed polymerization of methylenecyclopropane is disclosed.
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