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Browse by: INVENTOR PATENT HOLDER PATENT NUMBER DATE
 
 
Inventor:
Hagen; Helmut
Address:
Frankenthal, DE
No. of patents:
73
Patents:


1 2


Patent Number Title Of Patent Date Issued
RE32154 Production of 2-(o-alkylthiophenyl)-1,3-diazocycloalkene hydrohalides May 20, 1986
Production of new 2-(o-alkylthiophenyl)-1,3-diazacycloalkene hydrohalides by reaction of a benzo-thietane-2-spiro-2'-(1',3'-diazacycloalkane) with an alkyl halide, and the new 2-(o-alkylthiophenyl)-1,3-diazacycloalkene hydrohalides which are pharmaceuticals, auxiliaries for the textile a
7309802 Preparation of isoxazolin-3-ylacylbenzene December 18, 2007
A process is described for preparing isoxazoles of the formula I ##STR00001## where the substituents are as defined below: R.sup.1 is hydrogen, C.sub.1-C.sub.6-alkyl, R.sup.2 is C.sub.1-C.sub.6-alkyl, R.sup.3, R.sup.4, R.sup.5 are hydrogen, C.sub.1-C.sub.6-alkyl, or R.sup.4 and R.
6716989 Preparation of 2-alkyl-3-(4,5-dihydroisoxazol-3-yl) halobenzenes April 6, 2004
A novel process for preparing the compounds of the formula I ##STR1##where: n is 0, 1 or 2; R.sup.1, R.sup.2 are C.sub.1 -C.sub.6 -alkyl; R.sup.3, R.sup.4, R.sup.5 are hydrogen or C.sub.1 -C.sub.6 -alkyl, or R.sup.4 and R.sup.5 together form a bond; R.sup.6 is Cl, Br,which compri
6706886 Process and novel intermediates for preparing isoxazolin-3-ylacyl benzenes March 16, 2004
The present invention describes a process for preparing isoxazoles of the formula I ##STR1##where: R.sup.1 is hydrogen, C.sub.1 -C.sub.6 -alkyl, R.sup.2 is hydrogen, C.sub.1 -C.sub.6 -alkyl, R.sup.3, R.sup.4, R.sup.5 are each hydrogen, C.sub.1 -C.sub.6 -alkyl or R.sup.4 and R.su
6670482 Process and novel intermediates for preparing isoxazolin-3-ylacyl benzenes December 30, 2003
The present invention describes a process for preparing isoxazoles of the formula I ##STR1##where: R.sup.1 is hydrogen, C.sub.1 -C.sub.6 -alkyl, R.sup.2 is hydrogen, C.sub.1 -C.sub.6 -alkyl, R.sup.3, R.sup.4, R.sup.5 are each hydrogen, C.sub.1 -C.sub.6 -alkyl or R.sup.4 and R.su
6608209 Preparation of isoxazolin-3-ylacylbenzenes August 19, 2003
A process is described for preparing isoxazoles of the formula I ##STR1##wherein R.sup.1 is hydrogen, C.sub.1 -C.sub.6 -alkyl, R.sup.2 is C.sub.1 -C.sub.6 -alkyl, R.sup.3, R.sup.4, R.sup.5 are hydrogen, C.sub.1 -C.sub.6 -alkyl, or R.sup.4 and R.sup.5 together form a bond, R.sup.6
6603017 Preparation of 2-alkyl-3-(4,5-dihydroisoxazol-3-yl) halobenzenes August 5, 2003
A novel process for preparing the compounds of the formula I ##STR1##where: n is 0, 1 or 2; R.sup.1, R.sup.2 are C.sub.1 -C.sub.6 -alkyl; R.sup.3, R.sup.4, R.sup.5 are hydrogen or C.sub.1 -C.sub.6 -alkyl, or R.sup.4 and R.sup.5 together form a bond; R.sup.6 is Cl, Br,which compri
6548677 Method of producing 2-alkyl-3-(4,5-dihydroisoxazole-3-yl)-halobenzenes April 15, 2003
A novel process for preparing the compounds of the formula I ##STR1##where: n is 0, 1 or 2; R.sup.1, R.sup.2 are C.sub.1 -C.sub.6 -alkyl; R.sub.3, R.sub.4, R.sub.5 are hydrogen or C.sub.1 -C.sub.6 -alkyl, or R.sup.4 and R.sup.5 together form a bond; R.sup.6 is Cl, Br,which compri
6525204 Method for producing isoxazoline-3-yl-acyl benzene February 25, 2003
A process is described for preparing isoxazol-3-ylacylbenzenes. Also, novel intermediates for preparing isoxazol-3-ylacylbenzenes and novel processes for preparing the intermediates are described.
6469176 Method and novel intermediate products for producing isoxazolin-3-yl-acylbenzenenes October 22, 2002
The present invention describes a process for preparing isoxazoles of the formula I ##STR1##where: R.sup.1 is hydrogen, C.sub.1 -C.sub.6 -alkyl, R.sup.2 is hydrogen, C.sub.1 -C.sub.6 -alkyl, R.sup.3, R.sup.4, R.sup.5 are each hydrogen, C.sub.1 -C.sub.6 -alkyl or R.sup.4 and R.su
6197941 Reactive dyes with a heterocyclic anchor March 6, 2001
Reactive dyes of the formula I ##STR1##wherea is 1 or 2,b is 0 or 1,Y is vinyl or a radical of the formula C.sub.2 H.sub.4 Q, where Q is an alkali-detachable group,Het is the radical of a 5- or 6-membered aromatic hetero-cyclic ring having from 1 to 3 hetero atoms selected from the group
5886187 Benzene derivatives having a heterocyclic radical March 23, 1999
Benzene derivatives of the formula ##STR1## wheren is 0, 1 or 2,x is nitro or amino,Z is a direct bond or unsubstituted or substituted C.sub.1 -C.sub.6 -alkylene,Y is vinyl or a radical of the formula C.sub.2 H.sub.4 --Q, where Q is hydroxyl or a group which can be removed under alka
5783694 IR-absorbing phthalocyanines July 21, 1998
Compounds of the general formula I ##STR1## where the A radicals are, independently of one another, ##STR2## where the rings B and C can also, independently of one another, be substituted by C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, nitro, hydroxysulfonyl, benzoyl or
5565408 Cyanoquinoline compounds October 15, 1996
Cyanoquinoline compounds Ia or Ib ##STR1## where R.sup.1 is CH.dbd.C(CN).sub.2 ; CH.dbd.N--N.dbd.CH--(5-quinolyl); methylsulfonyl; CH.dbd.NOH; halogen; hydroxyl; nitro; cyano; unsubstituted or substituted C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy or C.sub.1 -C.sub.4 -alky
5561100 Pyrido-fused 4-oxo-4H-benzopyrans, their preparation and their use as antidotes October 1, 1996
Pyrido-fused 4-oxo-4H-benzopyrans I ##STR1## (m=0, 1 or 2; R.sup.1, R.sup.6 and R.sup.7 have the meanings stated in the description) and the salts of I, and herbicides which contain 2-(4-hetaryloxy)- and 2-(4-aryloxy)-phenoxyacetic acid derivatives or cyclohexenone derivatives as
5491123 Herbicides containing 3-aminobenzo(B)thiophenes as antidotes February 13, 1996
Herbicides contain one or more antagonistic 3-aminobenzo[b]thiophenes I ##STR1## wherein the variables on the compound of formula I are defined in the specification.A) the group consisting of the cyclohexenone derivatives orB) the group consisting of the 4-hetaryloxyphenoxyacetic acid de
5486618 Substituted 5-aminopyrazoles January 23, 1996
Substituted 5-aminopyrazoles I ##STR1## where R.sup.1 is C.sub.1 -C.sub.8 -alkyl, C.sub.1 -C.sub.8 -hydroxyalkyl, phenyl which may carry 1-3 of the following radicals: halogen, nitro, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio or --NR.sup.6 R.sup.7, and which may additionall
5424481 Preparation of methylsulfonylbenzoic acids June 13, 1995
A process for preparing methylsulfonylbenzoic acids comprises oxidizing the corresponding methylsulfonyltoluenes with nitric acid and air in sulfuric acid in the presence of vanadium or cobalt compounds.
5422335 Herbicides containing substituted 2-aminothiophenes June 6, 1995
A herbicidal composition containing one or more substituted 2-aminothiophenes of the formula I ##STR1## where R.sup.1 and R.sup.2 together from a C.sub.4 -alkylene chain to which a benzene ring may be fused,R.sup.3 is --CN or CX--R.sup.6, where R.sup.6 is hydroxyl, C.sub.1 -C.sub.4
5420307 2-amino-4-oxo-4H-benzopyrans, their preparataion and their use as antidotes May 30, 1995
2-Amino-4-oxo-4H-benzopyrans I ##STR1## (m=0, 1 or 2; R.sup.1 -R.sup.4 have the meanings stated in the description) and the salts of I, and herbicides which contain 2-(4-hetaryloxy)- and 2-(4-aryloxy)-phenoxyacetic acid derivatives and/or cyclohexenone derivatives as herbicidal a
5378677 Thiochromenone derivatives as antidotes, and herbicides containing them January 3, 1995
Herbicidal agents containing at least one thiochromenone of the formula I ##STR1## where n is 1, 2, 3 or 4, and the radicals R.sup.3 may have different meanings when n is>1;R.sup.1 is hydrogen; cyano; halogen; substituted or unsubstituted alkyl, aryl or hetaryl;a group --XR.sup.4
5342928 Benzisothiazole- and benzothiophene-azo dyes with a coupling component of the aniline series August 30, 1994
Azo dyes useful for dyeing or printing textile fibers or fabrics and containing novel aminobenzo heterocycles as diazo component have the formula ##STR1## where X is nitrogen or a radical of the formula CR.sup.6, where R.sup.6 is hydrogen, C.sub.1 -C.sub.4 -alkoxycarbonyl or C.su
5306815 Azo dyes with a coupling component of the quinoline series April 26, 1994
Azo dyes useful for dyeing or printing textile fibers or fabrics and for thermal transfer have the formula ##STR1## where R.sup.1 and R.sup.2 are each substituted or unsubstituted C.sub.1 -C.sub.10 -alkyl or substituted or unsubstituted C.sub.3 -C.sub.4 -alkenyl or R.sup.1 may al
5245058 Preparation of 1-nitroanthraquinone-2-carboxylic acids September 14, 1993
1-Nitroanthraquinone-2-carboxylic acids of the general formula I ##STR1## where X is hydrogen, chlorine or bromine, are prepared by oxidizing a 1-nitro-2-methylanthraquinone of the general formula II ##STR2## with nitric acid in an organic reaction medium.
5216171 2-amino-4-trichloropyridine derivatives June 1, 1993
2-Amino-4-trichloromethylpyridines of the general formula I ##STR1## where R.sup.1 is hydrogen or C.sub.1 -C.sub.8 -alkyl,R.sup.2 is C.sub.1 -C.sub.8 -alkyl, C.sub.5 -C.sub.8 -cycloalkyl, C.sub.2 -C.sub.4 -alkenyl or phenyl, benzyl or phenylsulfonyl,--CX--R.sup.3, --SO.sub.2 R.sup.3 or -
5198575 Preparation of nitrobenzoic and anthranilic acids March 30, 1993
Nitrobenzoic acids I ##STR1## (X.sup.1, X.sup.2 =fluorine, chlorine, bromine, hydrogen or nitro) are prepared by oxidizing the corresponding nitrotoluene II ##STR2## with nitric acid in the presence of sulfuric acid and vanadium(V) compounds, and anthranilic acids III ##S
5196573 Process for the preparation of sulfonated anthranilic acids March 23, 1993
A process for the preparation of 4-sulfonated anthranilic acids by sulfonation of ortho-nitrotoluenes with chlorosulfonic acid or oleum followed by oxidation of the methyl group and, finally, reduction of the nitro group.
5175265 Azo dyes with a diazo component of the 4-amino-7-nitrobenzisothiazole series and a coupling comp December 29, 1992
Benzisothiazole-azo dyes useful for dyeing synthetic fiber materials have the formula ##STR1## where X is hydrogen, chlorine, bromine, cyano or nitro and K is a radical of the formula ##STR2## where R.sup.1 is substituted or unsubstituted C.sub.1 -C.sub.12 -alkyl, substi
5167695 Derivatives of quinoline fused to a five-membered heterocyclic ring December 1, 1992
Quinoline derivatives fused to a five-membered heterocyclic ring and of the formula ##STR1## where R.sup.1 is hydrogen, halogen, carboxyl or substituted or unsubstituted alkyl,Y is nitrogen or C--R.sup.2, whereR.sup.2 is hydrogen, halogen, hydroxyl, alkoxy, alkylthio, substituted or
5130434 Preparation of 3-methylquinoline-8-carboxylic acid July 14, 1992
3-Methylquinoline-8-carboxylic acid I ##STR1## and derivatives thereof are prepared by reacting o-toluidine II or a derivative thereof ##STR2## with methacrolein II ##STR3## in 70-90% strength by weight sulfuric acid in the presence of iodine or of an iodine compound,
5104441 Herbicidal sulfonamides and their use to influence plant growth April 14, 1992
Substituted sulfonylureas of the formula I ##STR1## where R.sup.1 is hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.3 -C.sub.4 -alkenyl or alkynyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.3 -C.sub.6 -alkoxyalkyl, C.sub.4 -C.sub.6 -haloalkoxyalkyl or C.sub.5 -C.sub.6 -cycloalkyl,R.sup.2 is h
5059240 2,3-substituted 1,8-naphthyridines, their preparation and their use as antidotes October 22, 1991
2,3-substituted 1,8-naphthyridines of the general formula I ##STR1## where: R is hydrogen or C.sub.1 -C.sub.4 -alkyl (n=1 or 2)R.sup.1 is amino or substituted amino,XR.sup.5, where X is oxygen or sulfur and R.sup.5 is hydrogen, C.sub.1 -C.sub.12 -alkyl, C.sub.1 -C.sub.4 -alkoxycarbonyl-(
5035736 Herbicides which contain 2-(4-aryloxy)phenoxyacetic or -propionic acid derivatives and/or cycloh July 30, 1991
Herbicidal agents containing, as antagonistic agent, at least one naphthalene derivative of the formula I ##STR1## where R, R.sup.1, R.sup.2, and m are as defined in the specification and at least one herbicidal active ingredient from the group consisting of(a) 2(4-heteroaryloxy)- or
5006659 Preparation of 7-chloroquinoline-8-carboxylic acids April 9, 1991
7-Chloroquinoline-8-carboxylic acids of the formula (I) ##STR1## where R is hydrogen, chlorine or methyl, are prepared by direct oxidation of the corresponding 8-methylqunoline compound with nitric acid or nitrogen oxide in the presence of sulfuric acid and a heavy metal catalyst
4994564 Azo dyes with a diazo component of the 3-amino thiophene series and a coupling component of the February 19, 1991
Thien-3-ylazo dyes of the formula: ##STR1## where X is cyano, nitro, C.sub.1 -C.sub.6 -alkanoyl, substituted or unsubstituted benzoyl, substituted or unsubstituted phenyl or the radical COOR.sup.1 or CONR.sup.1 R.sup.2 where R.sup.1 and R.sup.2 are identical or different and each
4957608 Preparation of 8-bromomethyl-3-methylquinoline compounds September 18, 1990
A process for the preparation of 8-bromomethyl-3-methylquinoline compounds of the formula I ##STR1## where one or both substituents X are chlorine and, where relevant, the other substituent X is hydrogen, by bromination of the corresponding 8-methylquinoline compound in the prese
4857103 Influencing the development of crops with 7-chloroquinoline-8-carboxylic acids August 15, 1989
The development of crops is influenced by means of one or more 7-chloroquinoline-8-carboxylic acids of the general formula ##STR1## where R is fluorine, chlorine, bromine, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl.
4845226 Preparation of 8-bromomethyl-3-methylquinoline compounds July 4, 1989
A process for the preparation of 8-bromomethyl-3-methylquinoline compounds of the formula I ##STR1## where one of both substituents X are chlorine and, where relevant, the other substituent X is hydrogen, by bromination of the corresponding 8-methylquinoline compound in the prese
4832731 Quinoline-8-carboxylic acid azolides and their use as herbicides May 23, 1989
Quinoline-8-carboxylic acid azolides of the formula ##STR1## where A, X and R have the meanings given in the disclosure, and their use as herbicides.
4808212 Oxime esters of substituted quinoline-8-carboxylic acids and use thereof as herbicides February 28, 1989
Oxime esters of substituted quinoline-8-carboxylic acids of the formula ##STR1## where X is hydrogen, C.sub.1 -C.sub.4 -alkyl or halogen, Z is hydrogen or methyl, R.sup.1 is C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.4 -alkoxymethyl, C.sub.1 -C.sub.4 -alkoxyethyl, C.sub.1 -C.sub.4 -
4804404 2 and/or 3-trifluoromethyl-substituted quinoline 8-carboxylic acid derivatives and their use for February 14, 1989
Fluoroalkyl-substituted quinoline derivatives of the formula ##STR1## where R.sup.1 is chlorine, fluorine, hydroxyl, O.sup..crclbar. Met.sup..sym., C.sub.1 -C.sub.4 -alkoxy or a radical of the formula ##STR2## R.sup.2 and R.sup.3 independently of one another are each hydrogen,
4797148 Quinoline derivatives and their use for controlling undesirable plant growth January 10, 1989
Quinoline derivatives of the formula ##STR1## where R.sup.1, X, Y and Z have the meanings given in the disclosure, herbicides containing these compounds as active ingredients, and a process for combating unwanted plant growth.
4717416 3,7-dichloro-8-quinoline derivatives, and their use for controlling undersirable plant growth January 5, 1988
3,7-Dichloroquinoline derivatives which are substituted in the 8-position by --CH.dbd.CHR or --CH.dbd.NR.sup.5, and their use for controlling undesirable plant growth.
4715889 Quinoline derivatives and their use for controlling undesirable plant growth December 29, 1987
Quinoline derivatives of the formula ##STR1## where X, n, R.sup.1, R.sup.2 and Y have the meanings given in the description, are used for controlling undesirable plant growth.
4699983 2-amino-4-trichloromethylpyridine and its preparation October 13, 1987
2-Amino-4-trichloromethylpyridine of the formula I ##STR1## The compound is an effective nitrification inhibitor.
4667035 Substituted triazanonanes and process for their preparation May 19, 1987
The novel compounds of the general formula I ##STR1## where R and R.sup.1 are substituents and the rings A can be substituted and/or can carry fused rings, are useful intermediates for the preparation of, for example, dyes and active ingredients.
4632696 Dichloroquinoline derivatives for use as herbicides December 30, 1986
Dichloroquinoline derivatives of the formula ##STR1## where R.sup.1, X and Y have the meanings given in the claims, are prepared as described, and are used as herbicides.
4617395 Preparation of quinolines October 14, 1986
Quinoline and substituted quinolines are prepared by reacting aniline or a substituted aniline with an .alpha., .beta.-monounsaturated aldehyde in a high-boiling mineral oil by a method in which the high-boiling mineral oil is replaced when it becomes enriched with by-products, and the s
4589910 Novel 4'(benzisothiazo-5-yloxy)-phenylurea derivatives, their preparation and their use as herbi May 20, 1986
A 4'-(Benzisothiazol-5-yloxy)-phenylureas of the formula ##STR1## where R.sup.1 and R.sup.2 are each a saturated straight-chain or branched aliphatic radical of 1 to 10 carbon atoms, an unsaturated straight-chain or branched aliphatic radical of 3 to 10 carbon atoms, or an araliphati
4544755 Cleavage of phthalimides to amines October 1, 1985
Phthalimides of the formula I ##STR1## where R is a substituent and the ring A can be further substituted, are cleaved by a process in which a compound of the formula I is treated with an alkanolamine.The compounds prepared according to the invention are useful intermediates for
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